书目名称 | Molecular Symmetry, Super-Rotation, and Semiclassical Motion | 副标题 | New Ideas for Solvin | 编辑 | Hanno Schmiedt | 视频video | | 概述 | Presents fundamentally new ideas for describing dynamics in small molecules.Describes the application of molecular symmetry calculations to formulate new models for internal molecular motion.Compares | 丛书名称 | Springer Series on Atomic, Optical, and Plasma Physics | 图书封面 |  | 描述 | This book presents a range of fundamentally new approaches to solving problems involving traditional molecular models. Fundamental molecular symmetry is shown to open new avenues for describing molecular dynamics beyond standard perturbation techniques. Traditional concepts used to describe molecular dynamics are based on a few fundamental assumptions, the ball-and-stick picture of molecular structure and the respective perturbative treatment of different kinds of couplings between otherwise separate motions. The book points out the conceptual limits of these models and, by focusing on the most essential idea of theoretical physics, namely symmetry, shows how to overcome those limits by introducing fundamentally new concepts.. The book begins with an introduction to molecular symmetry in general, followed by a discussion of nuclear spin symmetry. Here, a new correlation between identical particle exchange and spin angular momentum symmetry of nuclei is exhibited.The central part of the book is the discussion of extremely floppy molecules, which are not describable in the framework of traditional theories. The book introduces a fundamentally new approach to describing the molecular | 出版日期 | Book 2017 | 关键词 | Symmetries in Molecules; Super-Rotor; Protonated Methane; Semiclassical Rotation; Nuclear Spin Symmetry; | 版次 | 1 | doi | https://doi.org/10.1007/978-3-319-66071-4 | isbn_softcover | 978-3-319-88170-6 | isbn_ebook | 978-3-319-66071-4Series ISSN 1615-5653 Series E-ISSN 2197-6791 | issn_series | 1615-5653 | copyright | Springer International Publishing AG 2017 |
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