| 书目名称 | Molecular Conformation and Organic Photochemistry |
| 副标题 | Time-resolved Photoi |
| 编辑 | Rasmus Y. Brogaard |
| 视频video | |
| 概述 | Nominated by the University of Copenhagen as outstanding thesis.Investigates how molecular rearrangements and chemical reactions compete on different time-scales after photo-excitation.Explores with a |
| 丛书名称 | Springer Theses |
| 图书封面 |  |
| 描述 | Rasmus Brogaard‘s thesis digs into the fundamental issue of how the shape of a molecule relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time scales of conformational changes. Combining theoretical and experimental efforts in femto-second time-resolved photoionization Rasmus Brogaard finds that a requirement for an efficient photochemical reaction is the prearrangement of the constituents in a reactive conformation. .Furthermore, he is able to show that by exploiting a strong ionic interaction between two chromophores, a coherent molecular motion can be induced and probed in real-time. This way of using bichromophoric interactions provides a promising strategy for future research on conformational dynamics. |
| 出版日期 | Book 2012 |
| 关键词 | Breaking and Formation of Chemical Bonds; Conformational Changes and Reactivity; Excited State Reactiv |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-3-642-29381-8 |
| isbn_softcover | 978-3-642-42674-2 |
| isbn_ebook | 978-3-642-29381-8Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
| issn_series | 2190-5053 |
| copyright | Springer-Verlag Berlin Heidelberg 2012 |
发表于 2025-3-21 18:31:03
