| 书目名称 | Milestones in Microwave Chemistry | | 编辑 | György Keglevich | | 视频video | | | 概述 | Includes supplementary material: | | 丛书名称 | SpringerBriefs in Molecular Science | | 图书封面 |  | | 描述 | .This book looks back on thirty-five years of microwave (MW)chemistry and explains how the application of the MW technique became anintegral part of R&D, eventually becoming recognized in industry. Further,it details how MW chemistry has undergone a dynamic development in the pastthree decades, one driven by the advent of increasingly sophisticatedprofessional MW reactors in place of the kitchen MW ovens used in earlieryears. A major part of the book shows how substitutions, esterifications,amidations, hydrolyses, alkylations, eliminations, dehydrations, condensations,cyclizations, C–C couplings and the modification of heterocycles can beperformed advantageously under MW irradiation, as the reaction times areshorter, while the selectivity and yields are higher; it also explains why inmost cases, the reactions can be performed under solvent-free conditions. MWirradiation within the sphere of organophosphorus chemistry is showcased andtypical reactions, such as the direct derivatization of phosphinic acids,alkylating esterifications, Diels–Alder reactions, the inverse Wittig-typereaction, fragmentations, the Arbuzov reaction, the synthesis ofα-hydroxyphosphonates and α-aminophosphona | | 出版日期 | Book 2016 | | 关键词 | Green Chemistry Microwaves; Green Synthesis Microwaves; History of Microwave Chemistry; Introduction to | | 版次 | 1 | | doi | https://doi.org/10.1007/978-3-319-30632-2 | | isbn_softcover | 978-3-319-30630-8 | | isbn_ebook | 978-3-319-30632-2Series ISSN 2191-5407 Series E-ISSN 2191-5415 | | issn_series | 2191-5407 | | copyright | Springer International Publishing Switzerland 2016 |
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发表于 2025-3-21 18:04:24
