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Titlebook: Metal Complexes in Aqueous Solutions; Arthur E. Martell,Robert D. Hancock Book 1996 Springer Science+Business Media New York 1996 biologic

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发表于 2025-3-21 19:14:47 | 显示全部楼层 |阅读模式
书目名称Metal Complexes in Aqueous Solutions
编辑Arthur E. Martell,Robert D. Hancock
视频video
丛书名称Modern Inorganic Chemistry
图书封面Titlebook: Metal Complexes in Aqueous Solutions;  Arthur E. Martell,Robert D. Hancock Book 1996 Springer Science+Business Media New York 1996 biologic
描述Stability constants are fundamental to understanding the behavior of metal ions in aqueous solution. Such understanding is important in a wide variety of areas, such as metal ions in biology, biomedical applications, metal ions in the environment, extraction metallurgy, food chemistry, and metal ions in many industrial processes. In spite of this importance, it appears that many inorganic chemists have lost an appreciation for the importance of stability constants, and the thermodynamic aspects of complex formation, with attention focused over the last thirty years on newer areas, such as organometallic chemistry. This book is an attempt to show the richness of chemistry that can be revealed by stability constants, when measured as part of an overall strategy aimed at understanding the complexing properties of a particular ligand or metal ion. Thus, for example, there are numerous crystal structures of the Li+ ion with crown ethers. What do these indicate to us about the chemistry of Li+ with crown ethers? In fact, most of these crystal structures are in a sense misleading, in that the Li+ ion forms no complexes, or at best very weak complexes, with familiar crown ethers such as l2
出版日期Book 1996
关键词biological; biology; chemistry; inorganic chemistry; metals; organic chemistry; stability
版次1
doihttps://doi.org/10.1007/978-1-4899-1486-6
isbn_softcover978-1-4899-1488-0
isbn_ebook978-1-4899-1486-6Series ISSN 0891-4540 Series E-ISSN 2945-5057
issn_series 0891-4540
copyrightSpringer Science+Business Media New York 1996
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Metal Complexes in Aqueous Solutions978-1-4899-1486-6Series ISSN 0891-4540 Series E-ISSN 2945-5057
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https://doi.org/10.1007/978-1-4899-1486-6biological; biology; chemistry; inorganic chemistry; metals; organic chemistry; stability
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Factors Governing the Formation of Complexes with Unidentate Ligands in Aqueous Solution. Some GeneWhen a unidentate ligand such as NH. or SCN. replaces a water molecule on a metal ion to form a complex in aqueous solution, several factors contribute to the final free energy of complex formation. This section summarizes these factors as they are presently understood.
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Chelating Ligands,The Chelate Effect. produces increased stability for the complexes of chelating ligands as compared with those of open-chain analogues. This is seen for the formation constants of complexes of Ni(II) with .-dentate polyamines, as compared with the analogous complexes with ammonia..
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Arthur E. Martell,Robert D. Hancockuth. The chapter argues that the ineffable reality, Brahman at the . level can be perceived as the reality in quietude since the identity relationship between . and Brahman completely diminishes the scope of any language or word. This leads Śaṅkara’s philosophy to a point of quietism since the knowe
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Arthur E. Martell,Robert D. Hancock understood independently of their religious context. Secondly, the observation is put forward that communication itself is part of human existence, exhibiting the same characteristics as other existential experiences. In particular, the situation of communicating subjective existence calls forward
发表于 2025-3-23 08:06:38 | 显示全部楼层
Arthur E. Martell,Robert D. Hancock understood independently of their religious context. Secondly, the observation is put forward that communication itself is part of human existence, exhibiting the same characteristics as other existential experiences. In particular, the situation of communicating subjective existence calls forward
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