Titlebook: Metal Catalyzed Reductive C-C Bond Formation; A Departure from Pre Michael J. Krische Book 2007 Springer-Verlag Berlin Heidelberg 2007 Alde

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Catalytic Reductive Coupling of Alkenes and Alkynes to Carbonyl Compounds and Imines Mediated by Hye transformations of enormous socioeconomicimpact, such as the Haber–Bosch process and the reduction of olefinic feedstocks. Despite considerableprogress across diverse areas of catalytic hydrogenation, reductive C–C bond formations mediated byhydrogen have, until recently, been restricted to the in

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pessimism

Nickel-Catalyzed Reductive Coupling of Dienes and Carbonyl Compounds,escribed. In the presence of Ni(cod).,trialkylsilanes (R.SiH) serve as reducing agents and promote ω-dienyl aldehydesto undergo intramolecular allylation with high regio- and stereoselectivity. In the presence of indium(I)iodide, Ni(acac). catalyzes double allylation of aldehydes with 1,3-butadiene

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Reductive Coupling of Unactivated Alkenes and Alkynes,the progress made in early transition metal and lanthanideseries catalytic processes using alkyl metals or silanes as the stoichiometric reductants and the progressmade in the use of late transition metals for the same reactions using silanes, stannanes and borohydridesas the reductant. The mechanis

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978-3-642-09198-8Springer-Verlag Berlin Heidelberg 2007

Heretical

Metal Catalyzed Reductive C-C Bond Formation978-3-540-72879-5Series ISSN 0340-1022 Series E-ISSN 1436-5049

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forthy

Michael J. KrischePresents critical reviews of the present position and future trends in modern chemical research.Short and concise reports on chemistry, each written by the world renowned experts.Still valid and usefu