书目名称 | Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields |
编辑 | Youngwook Park |
视频video | |
概述 | Presents the experimental manipulations of molecular states with electrostatic fields which were previously unexplored due to the limitation in the strength of applicable fields.Discusses how the stat |
丛书名称 | Springer Theses |
图书封面 |  |
描述 | .This book describes the manipulation of molecular properties, such as orientation, structure, and dynamics, of small molecules and molecular clusters isolated in cold inert matrices by using unprecedentedly strong external electrostatic fields. Manipulation of molecules with controllable external forces is a dream of chemists. Molecules are inherently quantum-mechanical systems, control of which potentially can lead to quantum technology, such as quantum sensing and computing..This book demonstrates a combination of the ice film nanocapacitor method and the matrix isolation technique enabled the application of intense external dc electric fields across the isolated molecules and molecular clusters. Changes in molecular states induced by fields were monitored by means of vibrational spectroscopy. Also, the book presents manipulations of the inversion tunneling dynamics of ammonia molecule and the dislocation of acidic proton in hydrogen chloride–water complex...The book shows that the vibrational spectroscopy with the aid of unprecedentedly strong dc electric field can provide rich information on the electrostatic behaviors of molecules and molecular clusters, which underlie the un |
出版日期 | Book 2020 |
关键词 | Manipulation of Molecules; Ice Film Nanocapacitor; Reflection–Absorption Infrared Spectroscopy; Homogen |
版次 | 1 |
doi | https://doi.org/10.1007/978-981-15-8693-4 |
isbn_softcover | 978-981-15-8695-8 |
isbn_ebook | 978-981-15-8693-4Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
issn_series | 2190-5053 |
copyright | The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor |