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Titlebook: Liquid-Phase Reaction Rate Constants; E. T. Denisov Book 1974 IFI/Plenum Data Company 1974 Atom.Pet.Substitution.chemical physics.chemical

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Bimolecular and Trimolecular ReactionsThe kinetics of a bimolecular reaction of the type A + B → reaction products is described by the following equation (where x is the concentration of starting material that has reacted): . whence
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Addition Reactions of Atoms and RadicalsHydrogen atoms add to oxygen with a diffusion-rate constant. The addition of oxygen to alkyl radicals is somewhat slower. Under conditions of liquid-phase oxidation, a high rate constant for the reaction of oxygen addition ensures the predominance of peroxy radicals.
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https://doi.org/10.1007/978-1-4684-8300-0Atom; Pet; Substitution; chemical physics; chemical reaction; experiment; kinetics; metals; molecule; nitrile
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978-1-4684-8302-4IFI/Plenum Data Company 1974
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Recombination and Disproportionation of Free Atoms and Radicalsaction conditions). In the stationary reaction regime, W. = 2k [X.]., where k is the rate constant for the reaction of two radicals or atoms X., Since the quantity 2k is always used in calculations, the quantities listed here in the tables are always these (doubled) values of the reaction rate constants.
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