Titlebook: Ligand Field; Energy Diagrams E. König,S. Kremer Book 1977 Springer Science+Business Media New York 1977 coordination chemistry.luminescenc

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Strong-Field Couplingmmetric (. — 1)-electron function times a function for the Nth electron. The coefficients of this expansion are the cfp (cf. Section 2.3). The method has been extended by Horie. and others. and may be readily generalized to the problem at hand, i.e., to an arbitrary configuration of inequivalent electron states in an arbitrary point group ..

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hese diagrams are limited in scope in that they can be used only for octahedral symmetry and for a limited number of terms. The present volume is an attempt to fill the gap by providing a reasonable nurober of complete and accurate ligand field energy diagrarns for dN configurations in the most comm

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Tensor Operator Algebra in Free Atoms and Ionsl harmonics .. = |.〉 then arise in a natural way as the simultaneous eigenfunctions of the Hamiltonian and the operators .. and .. of the square of the total angular momentum and of its . component. This fact is intimately related to the transformation properties of the |.〉 eigenvectors under rotati

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Weak-Field Couplingre . = ., .−1,..., −. (cf. Section 2.4). The effect of a ligand field of particular symmetry consists, in general, in splitting the free ion levels labeled by . into ligand field states. The decomposition is equivalent to the reduction .where ..(.) is subduced from representation .. of .(3) and wher

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