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Titlebook: Kinetics of Interface Reactions; Proceedings of a Wor Michael Grunze,Hans Jürgen Kreuzer Conference proceedings 1987 Springer-Verlag Berlin

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书目名称Kinetics of Interface Reactions
副标题Proceedings of a Wor
编辑Michael Grunze,Hans Jürgen Kreuzer
视频videohttp://file.papertrans.cn/544/543073/543073.mp4
丛书名称Springer Series in Surface Sciences
图书封面Titlebook: Kinetics of Interface Reactions; Proceedings of a Wor Michael Grunze,Hans Jürgen Kreuzer Conference proceedings 1987 Springer-Verlag Berlin
描述This book contains the proceedings of the first Workshop on Interface Phenomena, organized jointly by the surface science groups at Dalhousie University and the University of Maine. It was our intention to concentrate on just three topics related to the kinetics of interface reactions which, in our opinion, were frequently obscured unnecessarily in the literature and whose fundamental nature warranted an extensive discussion to help clarify the issues, very much in the spirit of the Discussions of the Faraday Society. Each session (day) saw two principal speakers expounding the different views; the session chairmen were asked to summarize the ensuing discussions. To understand the complexity of interface reactions, paradigms must be formulated to provide a framework for the interpretation of experimen­ tal data and for the construction of theoretical models. Phenomenological approaches have been based on a small number of rate equations for the concentrations or mole numbers of the various species involved in a par­ ticular system with the relevant rate constants either fitted (in the form of the Arrheniusparametrization) to experimental data or calculated on the basis of microscop
出版日期Conference proceedings 1987
关键词Chemisorption; adsorption; electron energy loss spectroscopy; oxidation; scattering; spectroscopy; surface
版次1
doihttps://doi.org/10.1007/978-3-642-72675-0
isbn_softcover978-3-642-72677-4
isbn_ebook978-3-642-72675-0Series ISSN 0931-5195 Series E-ISSN 2198-4743
issn_series 0931-5195
copyrightSpringer-Verlag Berlin Heidelberg 1987
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Nonequilibrium Desorption of Physisorbed Atomss from solid surfaces /1,2,3/. These arguments are based on the statement that in equilibrium the flux of particles leaving a surface must balance the flux of particles arriving at it. PALMER et al. /2/ have shown experimentally that even if the whole system is not in equilibrium, the relationship b
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Studies of Surface Kinetics Using Second-Harmonic Generationerage, composition, binding site [2], and molecular orientation on surfaces [3,4]. In addition SHG has been shown to reveal the symmetry of atomic order on surfaces [5]. It is thus able to monitor symmetry-changing surface phase transitions [6]. Here, the features of SHG that make it a unique tool f
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Direct Measurements of Surface Kinetics by Time-Resolved Electron Energy Loss Spectroscopyt capabilities and future impact. In this article we will illustrate the way in which TREELS can contribute to our understanding of surface rate processes, specifically chemical kinetics“ As part of this assessment, it is useful to consider the basis for TREELS. In particular, we will highlight two
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Adsorption-Desorption Kinetics: Some Commentslly defined as that state in which a small number of macroscopic variables, such as internal energy, entropy, volume and mole numbers, are independent of time and of the previous history of the system. At the microscopic level myriads of molecular collisions take place whose dynamics follow quantum
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Precursor Intermediates and Precursor-Mediated Surface Reactions: General Concepts, Direct Observatiward followed by a delineation of the rationale for the original proposal of die existence of these species. A number of cases where the direct experimental observation of precursor states has been presented are discussed, and a number of rate expressions describing precursor-mediated adsorption and
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The Role of Precursors in Molecular Chemisorption and Thermal Desorption32 with the discovery of physical adsorption. Seminal calculations performed by Lennard-Jones /2/ revealed that a molecule incident on a metal surface passes through a shallow potential energy minimum resulting from an attractive Van der Waals interaction. Indirect experimental evidence for the exis
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