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Titlebook: Key Structural Factors of Group 5 Metal Oxide Clusters for Base Catalytic Application; Shun Hayashi Book 2020 Springer Nature Singapore Pt

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978-981-15-7350-7Springer Nature Singapore Pte Ltd. 2020
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Concluding Remarks,onstituent metals, counter cations, and the local structures of base sites, affect their base catalytic performance. Based on these findings, strategies for further improvements and future prospects for the application of metal oxide clusters as base catalysts are suggested.
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Introduction,OMs have been applied as catalysts for acid/base-catalyzed, oxidation, photocatalytic, and electrochemical reactions by exploiting their controllable geometric structures and tunable chemical properties. Because POMs have atomically precise structures, a combination of experimental and theoretical s
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,Effect of Counter Cations on Base Catalysis of [Nb10O28]6−,eaction between benzaldehyde and phenylacetonitrile. The base catalytic activity of . was dependent on the alkyl chain length . of .; the initial reaction rate (.) increased monotonously with . and reached a plateau at . = 3. The catalytic activity of . decreased with the addition of tetraalkylammon
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Effect of Constituent Metals on Base Catalysis of Hexametalate Clusters, W) were studied. Mass spectrometry and elemental analysis revealed that the tetrabutylammonium salts of [M.O.]. (M = Ta, Nb) were partially protonated to form [H.M.O.]. under ambient conditions, whereas those of [M.O.]. (M = Mo, W) were not. The base catalytic activity increased in the order of [Mo
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