Titlebook: Interfaces in Lithium–Ion Batteries; Andrea Paolella Book 2024 The Editor(s) (if applicable) and The Author(s), under exclusive license to

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,Interfacial Reactions in Li–S and Li–O2 Batteries,he long term. The reactions at the cathode (positive electrode) in Li-air and Li–S cells involve the reversible reduction of elemental S and O. gas, respectively, and are fundamentally different from those in Li-ion cells. Neither of these technologies is an established commercial product yet.

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,Introduction to Lithium–Ion Batteries,-ion batteries are here summarized such as: loading, capacity, Coulombic efficiency, ionic conductivity and transference number. Based on these concepts, the role of interfaces will analyzed in details in following chapters.

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Interface at the Negative Electrode: The Solid Electrolyte Interface-SEI,omponents of electrolyte forming a solid electrolyte interface (SEI): a layer composed by reduction product as buffer between graphite electrode and liquid electrolyte. The chapter describes the side products of decomposition deposit over graphite anode during cycling.

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Electrolytes,A lithium–ion battery needs an electrolyte that is stable during operating voltage. The chapter aims to underline the role of the electrolyte and the possible configurations reported in literature (liquid, solid and hybrid systems).

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