Titlebook: Iron-Catalysed Hydrofunctionalisation of Alkenes and Alkynes; Mark Greenhalgh Book 2016 Springer International Publishing Switzerland 2016

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Mark Greenhalghal students at the University of Washington. These materials included handouts, practice problems, guides to reading research articles, quizzes, notes from student help sessions, and student emails. The primary goal of these written materials, and now this book, is to recreate the perspective of lea

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Introduction,ment of synthetic chemistry. The hydrofunctionalisation of alkenes and alkynes can be used for the construction of carbon-carbon and carbon-heteroatom bonds, and represent a potentially 100 % atom-economic process. Transition-metal-catalysed hydrofunctionalisation reactions have therefore found nume

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Iron-Catalysed Hydrosilylation of Alkenes and Alkynes,nes and alkynes using a bench-stable iron(II) pre-catalyst, which could be activated in situ. The reaction scope and limitations are presented along with preliminary mechanistic studies, which lead to a discussion of possible reaction mechanisms and future work required to investigate this method further.

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Iron-Catalysed Hydromagnesiation of Styrene Derivatives,eals with the development of an iron-catalysed methodology for the hydromagnesiation of styrene derivatives to give benzylic Grignard reagents. The reaction scope and limitations are presented along with a discussion of possible reaction mechanisms based on in-depth mechanistic studies.