Titlebook: Iridium Catalysts for Organic Reactions; Luis A. Oro,Carmen Claver Book 2021 The Editor(s) (if applicable) and The Author(s), under exclus

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Recent Advances in Iridium-Catalysed Transfer Hydrogenation Reactions,n (TH) reactions. The reduction of carbonyls, imines, alkenes and alkynes is considered. The TH of unsaturated alkene-carbonyl substrates and heterocycles is particularly studied. Recent results on the reduction of CO. are also included. Special attention is paid to THs performed in aqueous medium a

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Iridium-Catalyzed Asymmetric Hydrogenation,ring the last 10 years. We also present their application to the synthesis of complex molecules. The first section deals with the hydrogenation of unfunctionalized olefins or with poorly coordinative groups. The second section includes the advances made in the hydrogenation of functionalized olefins

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,Iridium-Catalyzed Undirected Homogeneous C–H Borylation Reaction,–H borylation of heteroarenes, arenes, and alkanes. Selectivity issues are principally highlighted in this chapter since no directed groups are included in these approaches, but improved ligands are responsible of the new trends instead. In parallel, mechanistic insights on the C–B bond formation an

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Iridium-Catalyzed Silylation,t catalytic cycles are commented, paying especial attention to those that are more representative of each type of process. The chapter is divided into two main types of reactions, namely, hydrosilylation and C–H bond silylation. The former deals with the hydrosilylation of polar unsaturated bonds (k

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Iridium Catalysts for Hydrogen Isotope Exchange,n of heavy and radioactive hydrogen isotopes, a wealth of synthetic labeling strategies have been forthcoming. Principle among all HIE methods are those developed using homogeneous iridium catalysts. This chapter covers major developments in (primarily homogeneous) iridium-centered catalysts for HIE

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Iridium-Catalyzed Homogeneous Hydrogenation and Hydrosilylation of Carbon Dioxide,ades. This chapter focuses on the progress made during recent years in the field of homogeneous iridium-catalyzed reduction of CO. by using hydrogen and/or silicon hydrides as reducing agents, comparing them with homogeneous catalysts based on other transition metals..The reported studies on iridium

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Electroreduction of Carbon Dioxide by Homogeneous Iridium Catalysts,the storage and transport of renewable energy. For this purpose, a range of catalysts for the electroreduction of CO. have been studied, and recent progress in the context of tuning catalytic properties and understanding their mechanism of action has been remarkable. For example, molecular approache

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978-3-030-69085-4The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Switzerl