| 书目名称 | Investigation of Reactions Involving Pentacoordinate Intermediates |
| 副标题 | The Mechanism of the |
| 编辑 | Peter A. Byrne |
| 视频video | |
| 概述 | Nominated by University College Dublin as an outstanding PhD thesis.Describes the first example of an effect common to examples of all Li salt-free Wittig reactions.Outlines the development of a new c |
| 丛书名称 | Springer Theses |
| 图书封面 |  |
| 描述 | In this thesis, the author outlines the discovery of an effect common to representative examples of all Li salt-free Wittig Reactions. The implications of such a universally applicable effect are that all such Wittig reactions occur through the same mechanism. Although the Wittig reaction was first discovered in 1953, its reaction mechanism has never been definitively settled with many different variants proposed and disproved. The work in this thesis shows conclusively that for [2+2] cycloadditions all Wittig reactions occur by the same irreversible mechanism. In addition, the author also describes a new chromatography-free method for the removal of phosphine oxide from the alkene crude product of the Wittig reaction. The work in this thesis has led to several publications in high-profile journals. |
| 出版日期 | Book 2012 |
| 关键词 | Alkene Z/E Ratio; Kinetic Control in the Wittig Reaction; Oxalyl Chloride; Oxaphosphetane cis/trans Rat |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-3-642-32045-3 |
| isbn_softcover | 978-3-642-43787-8 |
| isbn_ebook | 978-3-642-32045-3Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
| issn_series | 2190-5053 |
| copyright | Springer-Verlag Berlin Heidelberg 2012 |
发表于 2025-3-21 19:19:15
