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Titlebook: Introduction to Structural Chemistry; Stepan S. Batsanov,Andrei S. Batsanov Book 2012 Springer Science+Business Media Dordrecht 2012 cryst

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发表于 2025-3-21 19:43:51 | 显示全部楼层 |阅读模式
书目名称Introduction to Structural Chemistry
编辑Stepan S. Batsanov,Andrei S. Batsanov
视频video
概述Ample tables for practical work - not just for illustration.All numbers revised and corrected on most recent data.Covers fast-growing areas: high pressure, nano-matter.Includes supplementary material:
图书封面Titlebook: Introduction to Structural Chemistry;  Stepan S. Batsanov,Andrei S. Batsanov Book 2012 Springer Science+Business Media Dordrecht 2012 cryst
描述A concise description of models and quantitative parameters in structural chemistry and their interrelations, with 280 tables and >3000 references giving the most up-to-date experimental data on energy characteristics of atoms, molecules and crystals (ionisation potentials, electron affinities, bond energies, heats of phase transitions, band and lattice energies), optical properties (refractive index, polarisability), spectroscopic characteristics and geometrical parameters (bond distances and angles, coordination numbers) of substances in gaseous, liquid and solid states, in glasses and melts, for various thermodynamic conditions. Systems of metallic, covalent, ionic and van der Waals radii, effective atomic charges and other empirical and semi-empirical models are critically revised. Special attention is given to new and growing areas: structural studies of solids under high pressures and van der Waals molecules in gases. The book is addressed to researchers, academics, postgraduates and advanced-course students in crystallography, materials science, physical chemistry of solids.
出版日期Book 2012
关键词crystal structure; electronegativity; high pressure; molecular structure; phase transitions
版次1
doihttps://doi.org/10.1007/978-94-007-4771-5
isbn_softcover978-94-007-9396-5
isbn_ebook978-94-007-4771-5
copyrightSpringer Science+Business Media Dordrecht 2012
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发表于 2025-3-21 20:43:44 | 显示全部楼层
Atom,ensity and of various empirical systems of atomic radii (covalent, metallic, ionic) derived from the observed interatomic distances in molecules and solids, their polarizability and compressibility. Both covalent and ionic radii are shown to increase with the coordination number.
发表于 2025-3-22 02:31:49 | 显示全部楼层
Intermolecular Forces,ectron density maps, and polarizabilities. There is a correspondence, both in energy and geometry, between covalent and vdW bonding, whereas donor-acceptor interactions are intermediate between them. Hydrogen bonds are reviewed briefly, clearing some common misconceptions which over-estimate their importance.
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Amorphous State,mputer simulations and extreme-conditions experiments on dynamic ionization. In diluted solutions of salts, ions replace water molecules and are 4-coordinate, while in concentrated solutions ions coordinate water molecules around them in structures similar to solid hydrates.
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