Titlebook: Introduction to Statistical Thermodynamics; A Molecular Perspect Marcus Elstner,Qiang Cui,Maja Gruden Textbook 2024 The Editor(s) (if appli

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The Canonical EnsembleIn Chap. ., we derived the distribution.

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Application to Ideal Gases of Polyatomic MoleculesIn this chapter, we will apply the formalism developed so far to the ideal gas in detail, i.e., we will calculate the state sum.

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Application to Solid BodiesWe have described molecules in the gas phase using the discrete quantum mechanical representation. We also use this approach for solids. Again, we use models that allow an additive representation of energy; this leads to a product of state sums, which in turn allows the thermodynamic properties to be calculated in a relatively simple way.

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The Microscopic Entropyhese are not determined by the internal energy .. Rather, the central principle of . applies. While in mechanics we can understand the system behavior exclusively from the energy, its derivatives, and the forces on the atoms, in thermodynamics the knowledge of the energy does not allow an understand

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