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Titlebook: Interphases and Mesophases in Polymer Crystallization III; Giuseppe Allegra Book 20051st edition Springer-Verlag Berlin Heidelberg 2005 Cr

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M. Muthukumarg, durch die das überschüssige Verbrennungsgas ins Freie strömte, diente gleichzeitig zum Abziehen der Verbrennurgsgasproben für die Analysen. Zur Bestimmung des organischen Schwefels im Brenngas diente eine Versuchsanordnung nach der Ruhrgasmethode (SEEBAUM-KRECKE).
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Interphases and Mesophases in Polymer Crystallization III
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Polymer Crystallization Driven by Anisotropic Interactions,ive it the necessary flexibility to account for many features of polymer crystallization that have been observed experimentally. These ingredients are (1) a difference in attraction between neighboring (nonbonded) components, (2) attraction between parallel bonds, and (3) temperature-dependent flexi
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,Pre-Crystalline, High-Entropy Aggregates: A Role in Polymer Crystallization?,ng by cooling from the reference state(melt or solution) above the temperature .down to . > .; (ii) crystallization from the glass; (iii) crystallizationfrom a stable thermotropic mesophase. In all three cases we propose that structure developmentproceeds via high entropy pre-crystalline aggregates,
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,Topological Mechanism of Polymer Nucleation and Growth – The Role of Chain Sliding Diffusion and Enttering (SAXS). This confirmed that the induction period of crystallization from the melt corresponds to the process of nucleation, not to that of spinodal decomposition. This success is due to a significant increase in the scattering intensity (.) from the nuclei (10. times as large as is normal),
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Spinodal Crystallization of Polymers: Crystallization from the Unstable Melt,e to the orientation fluctuation of stiffsegments prior to crystal nucleation. Evidences for SD obtained from small-angle X-ray and neutronscattering (SAXS and SANS), depolarized light scattering (DPLS), Fourier-transform infrared spectroscopy(FT-IR) are discussed in detail in the case of the glass
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Modeling Polymer Crystallization,utions. These simulations reveal molecular mechanisms of nucleation and growth, and the accompanying free energy barriers, during the very early stages of crystallization. The simulation results are also analyzed by statistical mechanics theories. Major conclusions on the growth of density fluctuati
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