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Titlebook: Inorganic Reactions in Water; Ronald Rich Book 2007 Springer-Verlag Berlin Heidelberg 2007 Reaction Chemistry.Water.chemistry.inorganic ch

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发表于 2025-3-30 08:17:35 | 显示全部楼层
Vanadium through Dubnium,The relative stabilities of the Group 5 species, plus the pseudoanalog Pa, in acidic solutions, at least without strong ligands, appear to be: V. > Nb. ≥ Db. > Ta. > Pa.; .V. > Nb. > Ta. > Db. > Pa.; .V. >> Pa. > Nb. > Ta. > Db.; .Pa. > Db. > Ta. > Nb. > V..
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Chromium through Seaborgium,Oxidation numbers: mainly (II), (III) and (VI), as in Cr., Cr.O. and CrO.., plus (IV) and (V) in peroxo complexes etc.
发表于 2025-3-30 20:08:41 | 显示全部楼层
Manganese through Bohrium,Oxidation numbers: (II), (III), (IV), (V), (VI) and (VII), as in Mn., Mn.O., MnO., MnO.. (“hypomanganate”), MnO.. (manganate) and MnO.. (permanganate). Remarkably, all six oxidation states can be found, rarely or often, in a tetrahedral oxoanion, MnO...
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Nickel through Darmstadtium,Oxidation numbers: (I), (II), (III) and (IV), as in [Ni.(CN).]., Ni., and hydrated Ni.O. and NiO..
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Copper through Roentgenium,Oxidation numbers in classical compounds: (I), (II) and (III), as in Cu.O, “cuprous” oxide, CuO, “cupric” oxide, and Na.[Cu.(TeO.).] ⋅ 16H.O.
发表于 2025-3-31 10:32:44 | 显示全部楼层
Boron through Thallium, the Triels,Oxidation number in classical compounds: (III), as in both [BH.]. (due to the low electronegativity of B) and [B(OH).].. Non-classical [closo-CB.H.]. etc., from non-aqueous sources, are some of the most inert and weakly coordinating anions available.
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Nitrogen through Bismuth, the Pentels,Oxidation numbers: (−III), (−II), (−I), (I), (II), (III), (IV), (V) and other, as in NH., N.H., NH.OH, H.N.O., NO, HNO., NO., NO.. and N...
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