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Titlebook: Hydrogen Bonding in Biological Structures; George A. Jeffrey,Wolfram Saenger Book 1991 Springer-Verlag Berlin Heidelberg 1991 DNA.Peptide.

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书目名称Hydrogen Bonding in Biological Structures
编辑George A. Jeffrey,Wolfram Saenger
视频video
图书封面Titlebook: Hydrogen Bonding in Biological Structures;  George A. Jeffrey,Wolfram Saenger Book 1991 Springer-Verlag Berlin Heidelberg 1991 DNA.Peptide.
描述Hydrogen bonds are weak attractions, with a binding strength less than one-tenth that of a normal covalent bond. However, hydrogen bonds are of extraordinary importance; without them all wooden structures would collapse, cement would crumble, oceans would vaporize, and all living things would disintegrate into random dispersions of inert matter..Hydrogen Bonding in Biological Structures. is informative and eminently usable. It is, in a sense, a Rosetta stone that unlocks a wealth of information from the language of crystallography and makes it accessible to all scientists. (From a book review of Kenneth M. Harmon, Science 1992)
出版日期Book 1991
关键词DNA; Peptide; RNA; X-ray; amino acid; base; carbohydrates; electron diffraction; molecule; mutation; neutron d
版次1
doihttps://doi.org/10.1007/978-3-642-85135-3
isbn_softcover978-3-540-57903-8
isbn_ebook978-3-642-85135-3
copyrightSpringer-Verlag Berlin Heidelberg 1991
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Effect of Hydrogen Bonding on Molecular Structurevalent bonds, depending upon the polarizability of the covalent bonding in the molecule. For this reason it is greatest in conjugated systems, where it is a structural manifestation of the ., discussed in Chap. 1.
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Purines and Pyrimidinesrivatives have been used most successfully in the investigations of biological processes and have found application in pharmacology [520, 521]. The same is true for the barbiturates, where the main emphasis is in pharmaceutical industry.
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Definitions and Conceptsydrogens attached to fluorine atoms and the weakest hydrogen bonds involve those attached to carbon atoms. It has long been known that with very electronegative donor and acceptor atoms, the hydrogen bond resembles a covalent bond, whereas, with weakly electronegative atoms, it is primarily electrostatic [42].
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Metrical Aspects of Three- and Four-Center Hydrogen BondsBecause in the (zwitterionic) amino acids there is a numerical imbalance between the (three) donor properties of the.and the (four) acceptor properties of the −CO.., the proportion of three-center bonds is untypically high, amounting to almost three quarters of the total number of hydrogen bonds.
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