Titlebook: Homogeneous Gold Catalysis; LeGrande M. Slaughter Book 2015 Springer International Publishing Switzerland 2015 Bimetallic Cooperativity.Ca

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,Ligand Design in Gold Catalysis and Chemistry of Gold–Oxonium Intermediates,oxygen nucleophile (ketone, aldehyde, or ether) attacks a cationic gold-activated multiple bond. This oxonium intermediate, being a highly energetic species, has the potential to undergo further transformations such as electron transfer/rearrangement/protodeauration to form diverse products.

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执拗

Book 2015s all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science..The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emergi

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Gold-Catalyzed Transformation of Unsaturated Alcohols,and is mostly focused on reactions where the π-acidity appears to overcome the inherent Lewis acidity of the complexes for alcohol activation. Select examples from the literature which demonstrate advances made between 2011 and 2014 are presented.

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Gold-Catalyzed Domino Reactions, reports implying hydration, hydroxylation, and hydroamination as key starting point for cascade transformations. Domino processes implying 1,.-enynes, asymmetric domino transformations, and applications of all the presented processes in total synthesis are presented.

Cabg318

,Gold π-Complexes as Model Intermediates in Gold Catalysis,cterizing these key structures, advancements are gradually being made in placing them in the context of an overall catalytic cycle. As a result, a research field has emerged which is rich with potential for continued discovery and catalyst improvement.

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摇曳

Topics in Current Chemistryhttp://image.papertrans.cn/h/image/428115.jpg

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978-3-319-38396-5Springer International Publishing Switzerland 2015

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