Titlebook: Homo- and Heterobimetallic Complexes in Catalysis; Cooperative Catalysi Philippe Kalck Book 2016 Springer International Publishing Switzerl

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Binuclear Iridium Complexes in Catalysis, catalytic cycles involved in these reactions are presented. The reactivity of these complexes toward a variety of substrates and the intermetallic cooperation mechanisms that differentiate binuclear entities from their mononuclear counterparts are reviewed and analyzed in detail. Oxidative addition

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,Reactivity and Catalysis at Sites , to the [Ru–Ru] Bond,aving electronic configuration σ.π.δ.δ*.π*., is examined. It is shown that the stronger donor leads to longer metal–metal distances. The C–H bond activation and C–C bond formation are studied at axial site of a [Ru.(CO).]. core. Metal–metal and metal–ligand cooperation is exploited for catalytic alc

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Alkyne Activation Using Bimetallic Catalysts,m to coordinate to two metals in a variety of different arrangements. A number of well-characterised bimetallic complexes have been discovered that utilise the versatile coordination modes of alkynes to enhance the rate of a bimetallic catalysed process. Yet, for many other bimetallic catalyst syste

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The Catalytic Binuclear Elimination Reaction: Importance of Non-linear Kinetic Effects and Increaseusual rate or selectivity effects are observed. These effects can be exhibited by monometallic, heterobimetallic and even multimetallic systems. The present contribution looks exclusively at one of the simplest cases, namely, systems possessing simultaneously both mononuclear and dinuclear complexes

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,Reactivity and Catalysis at Sites , to the [Ru–Ru] Bond,ohol dehydrogenation to aldehyde and subsequent coupling with amine to access imine selectively. Catalytic carbene transfer reactions are discussed for a wide range of diruthenium(I,I) compounds. Catalytic utility of metal–metal multiply bonded diruthenium(II,III) compounds for C–H amination reaction is also discussed.