书目名称 | Highly Luminescent Lanthanide Complexes with Specific Coordination Structures | 编辑 | Kohei Miyata | 视频video | | 概述 | Nominated by Hokkaido University as an outstanding Ph.D. thesis.Provides a general introduction to the principle of luminescence from lanthanide ions, lanthanide complexes, and coordination polymers.F | 丛书名称 | Springer Theses | 图书封面 |  | 描述 | This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C–H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C–F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300°C) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry. | 出版日期 | Book 2014 | 关键词 | Coordination Structure; Lanthanide; Lanthanide Complex; Luminescence of Complexes; Phosphine Oxide | 版次 | 1 | doi | https://doi.org/10.1007/978-4-431-54944-4 | isbn_softcover | 978-4-431-56398-3 | isbn_ebook | 978-4-431-54944-4Series ISSN 2190-5053 Series E-ISSN 2190-5061 | issn_series | 2190-5053 | copyright | Springer Japan 2014 |
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