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Titlebook: High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes; A Study of Molecular Carola S. Vogel Book 2012 Springer-Verlag Berlin Heid

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书目名称High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes
副标题A Study of Molecular
编辑Carola S. Vogel
视频video
概述Nominated by the University of Erlangen-Nuremberg as an outstanding PhD thesis.Synthesis, structural and spectroscopic characterization of high valent iron nitride complexes.Addresses the search for i
丛书名称Springer Theses
图书封面Titlebook: High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes; A Study of Molecular Carola S. Vogel Book 2012 Springer-Verlag Berlin Heid
描述.Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts..
出版日期Book 2012
关键词Carbene Ligands; Crystal Structure Determination; High Valent Iron; Iron (V) nitride; Iron Nitrides; Mößb
版次1
doihttps://doi.org/10.1007/978-3-642-27254-7
isbn_softcover978-3-662-50905-0
isbn_ebook978-3-642-27254-7Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightSpringer-Verlag Berlin Heidelberg 2012
The information of publication is updating

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TIMENtol/3,5xyl: Unexpected Reactivity Resulting From Modifications of the Ligand Periphery,gh-valent metal complexes; thus, they are perfectly suitable to act as supporting ligands for small molecule activation in reactive coordination complexes. The steric bulk of NHC ligands is highly tunable and a variety of ligands can be conveniently synthesized.
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Carola S. Vogelrtant and useful solution methods of various types of stochastic control problems for jump diffusions and its applications. ..The types of control problems covered include classical stochastic control, optimal stopping, impulse control and singular control. Both the dynamic programming method and th
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Carola S. Vogels types of stochastic control problems for jump diffusions and its applications. ..The types of control problems covered include classical stochastic control, optimal stopping, impulse control and singular control. Both the dynamic programming method and the maximum principle method are discussed, a
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