书目名称 | High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes |
副标题 | A Study of Molecular |
编辑 | Carola S. Vogel |
视频video | |
概述 | Nominated by the University of Erlangen-Nuremberg as an outstanding PhD thesis.Synthesis, structural and spectroscopic characterization of high valent iron nitride complexes.Addresses the search for i |
丛书名称 | Springer Theses |
图书封面 |  |
描述 | .Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.. |
出版日期 | Book 2012 |
关键词 | Carbene Ligands; Crystal Structure Determination; High Valent Iron; Iron (V) nitride; Iron Nitrides; Mößb |
版次 | 1 |
doi | https://doi.org/10.1007/978-3-642-27254-7 |
isbn_softcover | 978-3-662-50905-0 |
isbn_ebook | 978-3-642-27254-7Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
issn_series | 2190-5053 |
copyright | Springer-Verlag Berlin Heidelberg 2012 |