书目名称 | Functionalization of Carborane via Carboryne Intermediates | 编辑 | Da Zhao | 视频video | | 概述 | Nominated by The Chinese University of Hong Kong as an outstanding Ph.D. thesis.Presents groundbreaking new work in carborane chemistry.Inspires future work on synthetic, cluster, and materials chemis | 丛书名称 | Springer Theses | 图书封面 |  | 描述 | .This thesis focuses on the development of new methods of functionalizing carboranes using .o.-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and more. However, the limited number of efficient synthetic methods for obtaining functional carborane materials has restricted their applications. The methodologies established in this thesis represent simple, yet powerful strategies to assemble previously inaccessible, useful complex molecules, which will also have a significant impact on future synthetic, cluster and materials chemistry. Moreover, it discusses the first method for the in situ generation of electrophilic boron radical using photocatalysis. . | 出版日期 | Book 2016 | 关键词 | Synthetic Methods; Carborane Functionalization; Cluster Compounds; Cycloaddition; C−H Insertion; Multiple | 版次 | 1 | doi | https://doi.org/10.1007/978-981-10-1569-4 | isbn_softcover | 978-981-10-9389-0 | isbn_ebook | 978-981-10-1569-4Series ISSN 2190-5053 Series E-ISSN 2190-5061 | issn_series | 2190-5053 | copyright | Springer Science+Business Media Singapore 2016 |
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