| 书目名称 | Free-Radical Synthesis and Functionalization of Heterocycles |
| 编辑 | Yannick Landais |
| 视频video | |
| 概述 | Provides readers with an overview of free-radical chemistry as an environmentally benign synthetic strategy to access heterocycles.Emphasizes the high bond forming efficiency of using radical cascade |
| 丛书名称 | Topics in Heterocyclic Chemistry |
| 图书封面 |  |
| 描述 | .This volume describes the recent developments in the free-radical mediated synthesis and elaboration of heterocycles. The first chapter, dealing with radical cascade processes illustrates the power and the beauty of radical chemistry with some striking examples of total synthesis of complex natural heterocycles. As organic chemists strive towards sustainability, radical chemistry has recently seen major advances and efforts in this direction, including C-H activation of arenes and unactivated alkyl groups. Photochemical activation, for a long time the preferred mode of activation in radical chemistry has also seen an unexpected revival with the advent of visible light metal- and organocatalyzed photoredox processes. A survey of these emerging areas is provided along with the concepts at the origin of these developments. ..The venerable Minisci reaction allows for direct access to functionalized heterocycles. This process has lately seen an interesting renaissance and is discussed in this volume. Addition of heteroatom-centered radicals onto unsaturated systems constitutes another powerful method to construct heterocycles. Examples of such a strategy are proposed along with the for |
| 出版日期 | Book 2018 |
| 关键词 | Radical cascades; Photocatalysis; Minisci reaction; Free-radical synthesis; heteroatom-centered radicals |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-3-319-89521-5 |
| isbn_softcover | 978-3-030-07792-1 |
| isbn_ebook | 978-3-319-89521-5Series ISSN 1861-9282 Series E-ISSN 1861-9290 |
| issn_series | 1861-9282 |
| copyright | Springer International Publishing AG, part of Springer Nature 2018 |
发表于 2025-3-21 18:14:30
