Titlebook: Expanded Clays and Other Microporous Solids; Mario L. Occelli,Harry E. Robson Book 1992Latest edition Springer Science+Business Media New

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Preparation and Properties of Pillared Synthetic Boron-Containing Saponite,gO. The alumina-pillared synthetic boron-containing saponite [designated as Al-PSBCS(X), X is the added boron moles that are based on Mg=6 moles in the preparation] possessed both higher cumene dealkylation activity [93.4 wt.%] and better benzene selectivity [74.0 wt.%] than alumina-pillared non-bor

overture

Surface and Cracking Properties of Expanded Clays Dried with a Supercritical Fluid,ials with high (450–650 m./g) surface area, macroporosity (350–400 m./g), and pore volume (~1.5 cc/g), which are thermally stable to 800°C. If drying at supercritical conditions is replaced by air drying (AD), the clays lose their macroporosity, and in the case of montmorillonite, a large decrease i

Accommodation

TEM Characterization of Pillared Rectorites,with Al.0.-clusters. The regular 1:1 interstratification of mica-like and montmorillonite-like layers yield (variable) interlayer spacings of about 28Å. Nonuniform pillar distributions have been attributed to layer charge heterogeneity and to pillar deformation. Other defects, like stacking faults,

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Anionic Clays: Trends in Pillaring Chemistry, 1930; Read and Dixon 1933; Frondel 1941). A great variety of names is used in relation to the composition and the nature of the polytypes of these minerals (hydrotalcite, manasseite, pyroaurite, sjögrenite, stichtite, takovite, honessite, meixnerite...); Drits et al. 1987 proposed a systematic nome

欢腾

Preparation and Characterization of Borate Pillared Anionic Clays,of the anionic clays are strong bases. In the literature, a polyoxometalate of transition metals, such as molybdenum, tungsten, or vanadium, was usually the subject to introduce into the interlayer space of anionic clays. However, the composition of these polyoxometalates is pH dependent, and these

步兵

Layered Silicates: The Protonation Behavior of KHSi2O5,potassium hydrogen disilicate, KHSi.O.. Crystals of KHSi.O. were prepared hydrothermally and obtained in high yield. Protonation of this material with excess acid rapidly produces crystalline H.Si.O.. Although the bulk crystal morphology is retained during protonation, significant reorganization of

maculated

Synthesis of Dioctahedral 2:1 Layer Silicates in an Acid and Fluoride Medium,ydrogel, hydrothermal treatment of natural minerals, or by the melting of a mixture of miscellaneous reagents in the absence of water. Hydrothermal synthesis is the most commonly used method. Hydroxide ions are involved as a mineralizing or mobilizing agent of the structural elements. Fluoride ions

jealousy

Direct Synthesis of Novel Intercalated Layer Silicates of the Metal Silicate Type,(poly-{dimethyl-diallyl-ammonium chloride}) was intercalated into the silicate during the crystallization. Composition, structure, and the x-ray diffraction patterns of the new silicate do not fit any known layered silicate. The new silicate differs from the former ones by having a higher structural