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Titlebook: Endohedral Fullerenes: Electron Transfer and Spin; Alexey A. Popov Book 2017 Springer International Publishing AG 2017 Charget Transport.E

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书目名称Endohedral Fullerenes: Electron Transfer and Spin
编辑Alexey A. Popov
视频video
概述First monograph on endohedral fullerenes since 2001.First systematic description of the electron transfer in endohedral fullerenes for all phases.Comparison of electrochemical and STM data.Magnetism o
丛书名称Nanostructure Science and Technology
图书封面Titlebook: Endohedral Fullerenes: Electron Transfer and Spin;  Alexey A. Popov Book 2017 Springer International Publishing AG 2017 Charget Transport.E
描述This book discusses recent progress in endohedral fullerenes – their production and separation techniques, as well as their characterization and properties. Furthermore, the book delves into the all-important issue of stability by investigating electron transfer between the encapsulated metal species and the carbon cage. It also reviews spin-based phenomena caused by the shielding of endohedral spin by the fullerene, and analyzes formation of the spin states by charge transfer as studied by electron spin resonance. Tuning of charge states of endohedral species and of spin states of both the cage and the cluster are explained. Finally, the book considers the recent discovery of magnetism in some endohedral fullerenes, and the potential for quantum computing.
出版日期Book 2017
关键词Charget Transport; Electron Transfer; Endohedral Fullerenes; Endohedral Metallofullerenes; Magnetic Reso
版次1
doihttps://doi.org/10.1007/978-3-319-47049-8
isbn_softcover978-3-319-83648-5
isbn_ebook978-3-319-47049-8Series ISSN 1571-5744 Series E-ISSN 2197-7976
issn_series 1571-5744
copyrightSpringer International Publishing AG 2017
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Ions of Endometallofullerenes in the Gas Phase,pectrometry was the first method to indicate the possible existence of EMFs, which happened several years before the discovery of their bulk arc-discharge synthesis. The studies of the ions of EMFs in the gas phase often preceded studies by other techniques that require substantial quantities of EMF
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Scrutinizing the Endohedral Space: Superatom States and Molecular Machines,ke metal-organic frameworks. The first topic describes the special properties of electronic states, whose orbitals are not bound to specific atoms, but rather confined to vacuum region within the hollow molecules or materials. The second topic describes the dynamics of endohedral clusters within hol
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Electron Spin Resonance Studies of Metallofullerenes,lyzing the hyperfine couplings of their ESR spectra. The chapter describes the electron spin resonance and the tunable paramagnetic properties of M@C. (M = Sc, Y, La), Sc.C.@C., Y.@C.N, TiSc.N@C., and others. The electron spin manipulation based on these paramagnetic species has been realized by cha
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Electron Spin Resonance of Lanthanide EMFs,ns of La@C., La.@C., and their reduced anion and radical species is presented. Also discussed are ESR studies of lanthanide metallofullerene with high spin state, including Eu@C., Eu@C., Gd@C., and Gd.@C.N.
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Nuclear Magnetic Resonance Spectroscopy of Endohedral Metallofullerenes with Paramagnetic Metal Ionries of Ce-EMFs, analysis of the temperature dependence of chemical shifts in NMR spectra proved that the main contribution to the paramagnetic shifts is the dipolar “pseudocontact” term. As this term includes geometric parameters of the molecule, position and dynamics of endohedral metal atoms can
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