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Titlebook: Enantiomer Separation; Fundamentals and Pra Fumio Toda Book 2004 Springer Science+Business Media B.V. 2004 chromatography.crystal.crystalli

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Christian Hönemann,Marie-Luise Rübsamar recognition. The “lock-and-key” model that was proposed by Fischer is commonly useful for understanding the phenomenon of the molecular recognition. The complementarily of a lock and a key is essential to this model, in which the lock is the molecular receptor and the key is the substrate that is
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syntheses or biological reactions are generally employed for this purpose. However, even today, an efficient and practical method for the separation of racemates via crystallization is still a useful key technology for preparing optically active compounds in an industrial-scale production. In this
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https://doi.org/10.1007/978-3-642-95802-1ronmentally friendliness. Typical enzymatic reactions used for the organic synthesis are shown in Figure 1. Especially, hydrolytic enzymes for kinetic resolutions of racemates have been utilized widely because of their high stabilities, wide subs f trate specificities, lack of cofactor requirements
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https://doi.org/10.1007/978-3-642-13099-1rly trails and recent advances. A comprehensive compendium of referece is provides. Enantiomers are separated by three types of molecular interactions: hydrogen-bonding, coordination and (.) inclusion. Consequently, chiral stationary phases are comprised of dipeptides, metal chelates and (modified)
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