Titlebook: Electrons in Fluids; The Nature of Metal— Joshua Jortner,Neil R. Kestner Book 1973 Springer-Verlag, Berlin · Heidelberg 1973 Absorption.Dif

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https://doi.org/10.1007/978-94-017-1911-7pendent of the metal in solution over the concentration range from 0.005 M to 0.05 M. Results are interpreted in terms of new solvent-containing species in the presence of solvated electrons. Solvent molecules in these species are polarized by the solvated electron and show weakened N-H bonds in the presence of increased electron density.

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Ultrafast Optical Processes,ution limited by the time width of the picosecond pulse. The techniques of picosecond spectroscopy were utilized for the study of the relaxation of a quasi-free electron to the localized electron state in water.

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Raman Spectroscopy of Metal-Ammonia Solutions,e solute in this concentration region. The intensity of the scattered radiation was found to decrease with increasing metal concentration and has been attributed to the absorbance of these solutions. The Raman effect in F-centers is discussed and compared to metal-ammonia solutions.

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Theory of Electrons in Polar Fluids,ons are compared with each other and with experimental data. These models are capable of explaining qualitatively, and in most cases, quantitatively, the effects of variables such as temperature, pressure, and the molecular structure and density of the solvent. These theories are then used to make b

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The Effect of Electrolytes on the Hydrogen-Bonded Structure of Liquid Ammonia, (to higher frequency) relative to pure ammonia occurred in a solution of sodium perchlorate. These results are interpreted in terms of a model for the effect of electrolytes on the ammonia solvent structure.

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Metal Solutions in Amines and Ethers,rown” and “cryptate” to the solution. Studies are also presented which provide evidence for the existence of the monomer (M) and alkali anion (M.) species. Finally a general equilibrium scheme for all species is presented and the influence of the solvent is discussed.

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Quasi-Free Electrons in Polar Liquids,uasi-free electrons in solution by optical transition: resolution of the absorption spectrum of solvated electrons in various solvents; rate of loss of kinetic energy of quasi-free electrons in solution from . spectra; energy distribution curve for electrons emitted by solutions in vacuum.