Titlebook: Electronic and Vibronic Spectra of Transition Metal Complexes I; H. Yersin Book 1994 Springer-Verlag Berlin Heidelberg 1994 Transition Met

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Electronic and Vibronic Spectra of Transition Metal Complexes I978-3-540-48464-6Series ISSN 0340-1022 Series E-ISSN 1436-5049

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0340-1022 Overview: 978-3-662-14893-8978-3-540-48464-6Series ISSN 0340-1022 Series E-ISSN 1436-5049

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Vibrational progressions in electronic spectra of complex compounds indicating strong vibronic coupvibronic coupling. In the case when the vibrational structure is resolved into a progression of individual bands, a vibronic analysis can be carried out which compares a theoretical line shape function with the intensity profile measured in the experiment. From this Franck-Condon type procedure the

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Sharp-line electronic spectra and metal-ligand geometry,c transitions. The positions of, and especially the splittings within, these lines are strongly influenced by the angular positions and orientations of the ligands. The angular overlap model (AOM) is well suited to treat the exact geometry as part of the ligand field potential. It is possible in som

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Competition between ligand centered and charge transfer lowest excited states in bis cyclometalatedeneral formula [M(C∩N).N∩N]., M=Rh., Ir. (HC∩N=2-phenylpyridine or 2-(2-thienyl) pyridine; N∩N-2,2′-bipyridine or ethylenediamine) are summarized. The nature of the lowest excited states of the compounds is discussed on the basis of their absorption, luminescence and luminescence line narrowing spec

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