| 书目名称 | Electronic Communication in Heterometallated Porphyrin Oligomers |
| 编辑 | Jonathan Cremers |
| 视频video | |
| 概述 | Nominated as an outstanding PhD thesis by the University of Oxford, United Kingdom.Provides a comprehensive and readable account of a new field of research.Is suitable for new graduate students and ex |
| 丛书名称 | Springer Theses |
| 图书封面 |  |
| 描述 | .This book cuts across the divisions of organic, inorganic, and physical chemistry. It describes new methods for creating π-conjugated porphyrin oligomers with precisely defined sequences of zinc and copper metal cations, and how EPR spectroscopy was used to investigate the dipolar and exchange coupling between the paramagnetic copper(II) centres..Porphyrins are a group of heterocyclic macrocycle organic compounds that play an important role in our everyday life and can for example be found in blood where they form a red complex with iron (haem). Various metallic elements can be inserted into a porphyrin and changing the coordinated metal is an excellent way to influence the chemical and physical properties of these molecules.. .Focusing on 3 metals - zinc, magnesium and copper - the author established new methods for creating π-conjugated porphyrin oligomers and lastly presents the synthesis and investigation of two novel porphyrin nanoballs. Givingthe template-directed strategy the author developed for constructing these molecules, this work could provide access to other related nano-cages.. |
| 出版日期 | Book 2020 |
| 关键词 | Porphyrin Nanostructures; UV-vis-NIR Titrations; Quantum Interference; EPR Spectroscopy; Molecular Inter |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-3-030-39101-0 |
| isbn_softcover | 978-3-030-39103-4 |
| isbn_ebook | 978-3-030-39101-0Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
| issn_series | 2190-5053 |
| copyright | Springer Nature Switzerland AG 2020 |
发表于 2025-3-21 17:48:39
