| 书目名称 | Electrolytes at Interfaces | | 编辑 | S. Durand-Vidal,J. -P. Simonin,P. Turq | | 视频video | | | 丛书名称 | Progress in Theoretical Chemistry and Physics | | 图书封面 |  | | 描述 | The aim of this book is to provide the reader with a modernpresentation of ionic solutions at interfaces, for physical chemists,chemists and theoretically oriented experimentalists in this field.The discussion is mainly on the structural and thermodynamicproperties, in relation to presently available statistical mechanicalmodels. Some dynamic properties are also presented, at a morephenomenological level. .The initial chapters are devoted to the presentation of some basicconcepts for bulk properties: hydrodynamic interactions,electrostatics, van der Waals forces and thermodynamics of ionicsolutions in the framework of a particular model: the mean sphericalapproximation (MSA). Specific features of interfaces are thendiscussed: experimental techniques such as in-situ X-ray diffraction,STM and AFM microscopy are described. Ions at liquid/air, liquid/metaland liquid/liquid interfaces are considered from the experimental andtheoretical viewpoint. Lastly some dynamic (transport) properties areincluded, namely the self-diffusion and conductance of small colloids(polyelectrolytes and micelles) and the kinetics of solute transfer atfree liquid/liquid interfaces. | | 出版日期 | Book 2002 | | 关键词 | AFM; STM; colloid; diffraction; dynamics; kinetics; metal; statics; thermodynamics; transport | | 版次 | 1 | | doi | https://doi.org/10.1007/0-306-46940-5 | | isbn_softcover | 978-1-4020-0406-3 | | isbn_ebook | 978-0-306-46940-4Series ISSN 1567-7354 Series E-ISSN 2215-0129 | | issn_series | 1567-7354 | | copyright | Springer Science+Business Media B.V. 2002 |
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发表于 2025-3-21 17:18:41
