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Titlebook: Electrical Double Layer at a Metal-dilute Electrolyte Solution Interface; G. A. Martynov,R. R. Salem Textbook 1983 Springer-Verlag Berlin

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书目名称Electrical Double Layer at a Metal-dilute Electrolyte Solution Interface
编辑G. A. Martynov,R. R. Salem
视频video
丛书名称Lecture Notes in Chemistry
图书封面Titlebook: Electrical Double Layer at a Metal-dilute Electrolyte Solution Interface;  G. A. Martynov,R. R. Salem Textbook 1983 Springer-Verlag Berlin
描述Most of the properties of a metal-electrolyte interface, even the spe­ cific nature of an electrode reaction, proneness of a metal to cor­ rosion, etc., are primarily determined by the electrical double layer (EDL) at this boundary. It is therefore no surprise that for the last, at least, one hundred years intent attention should have been centered on EDL. So much of material has been gathered to date that we are easi­ ly lost in this maze of information. A substantial part of the attempts to systematize these facts is made at present within the framework of thermodynamics. Such a confined approach is undoubtedly inadequate. The Gouy-Chapman theory and the Stern-Grahame model of the dense part of EDL developed 40-70 years ago, tailored appropriately to suit the occasion, inevitably underlie any description of EDL. This route is rather too narrow to explain all the facts at our disposal. A dire necessity has thus arisen for widening the principles of the micros­ copic theory. This is precisely the objective of our monograph. Fur­ thermore, we shall dwell at length on the comparison of the theory with experiment: without such a comparative analysis, any theory, however elegant it may
出版日期Textbook 1983
关键词Doppelschicht; Elektrolyt; Interface; Metall; Solution; Sorption; adsorption; electrolyte; metals; thermodyna
版次1
doihttps://doi.org/10.1007/978-3-642-48700-2
isbn_softcover978-3-540-11995-1
isbn_ebook978-3-642-48700-2Series ISSN 0342-4901 Series E-ISSN 2192-6603
issn_series 0342-4901
copyrightSpringer-Verlag Berlin Heidelberg 1983
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,Charakteristik der Röhre (Ahb. 15),lute electrolyte solutions. Here we shall continue to analyse this system and show that it includes two dimensionless parameters: the dimensionless ion charge . and the dimensionless electrode charge .. As the electrolyte concentration decreases, . tends to zero, while . increases. Therefore, in the
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https://doi.org/10.1007/978-3-642-60304-4II) and show that in the presence of specific adsorption forces this system leads to the Stern isotherm (in the preceding chapter we demonstrated that in the absence of these forces the systems leads to the Gouy-Chapman and Wagner-Onsager-Samaras equations). Thus, using system (81), (82), one can co
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https://doi.org/10.1007/978-3-642-60693-9ent on surface tension of a (liquid) electrode σ on the potential ., and also the differential capacity curves C.(.) for a metal-solution interface. Unfortunately, the information carried both by the former and the latter is identical, to a considerable extent. Indeed, it is known from thermodynamic
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https://doi.org/10.1007/978-3-662-25671-8be on its basis the most typical features of the zero-charge point (§ 20) and the integral capacity curves (§ 21). At the same time, we shall take every opportunity to compare theory and experiment (as we have already noted, the results of such a comparative analysis are not in favour of the theory)
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Broder J. Merkel,Britta Planer-Friedrich of electrochemistry) of its existence has not been provided so far. The situation is quite different for the electronic capacitor. It does exist at a metal surface. This unambiguously follows from the physical facts reliably established long ago: namely, the existence of free conduction electrons i
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