书目名称 | Electrical Double Layer at a Metal-dilute Electrolyte Solution Interface | 编辑 | G. A. Martynov,R. R. Salem | 视频video | | 丛书名称 | Lecture Notes in Chemistry | 图书封面 |  | 描述 | Most of the properties of a metal-electrolyte interface, even the spe cific nature of an electrode reaction, proneness of a metal to cor rosion, etc., are primarily determined by the electrical double layer (EDL) at this boundary. It is therefore no surprise that for the last, at least, one hundred years intent attention should have been centered on EDL. So much of material has been gathered to date that we are easi ly lost in this maze of information. A substantial part of the attempts to systematize these facts is made at present within the framework of thermodynamics. Such a confined approach is undoubtedly inadequate. The Gouy-Chapman theory and the Stern-Grahame model of the dense part of EDL developed 40-70 years ago, tailored appropriately to suit the occasion, inevitably underlie any description of EDL. This route is rather too narrow to explain all the facts at our disposal. A dire necessity has thus arisen for widening the principles of the micros copic theory. This is precisely the objective of our monograph. Fur thermore, we shall dwell at length on the comparison of the theory with experiment: without such a comparative analysis, any theory, however elegant it may | 出版日期 | Textbook 1983 | 关键词 | Doppelschicht; Elektrolyt; Interface; Metall; Solution; Sorption; adsorption; electrolyte; metals; thermodyna | 版次 | 1 | doi | https://doi.org/10.1007/978-3-642-48700-2 | isbn_softcover | 978-3-540-11995-1 | isbn_ebook | 978-3-642-48700-2Series ISSN 0342-4901 Series E-ISSN 2192-6603 | issn_series | 0342-4901 | copyright | Springer-Verlag Berlin Heidelberg 1983 |
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