| 书目名称 | Efficient Control and Spontaneous Transitions | | 编辑 | Miranda Louwerse | | 视频video | | | 概述 | Nominated as an outstanding PhD thesis by Simon Fraser University, Canada.Advances understanding of rare events in thermodynamic systems.Defines a thermodynamic measure of the relevance of a particula | | 丛书名称 | Springer Theses | | 图书封面 |  | | 描述 | .This thesis addresses deep questions that cut to the physical and informational essence of central chemical quantities such as transition paths and reaction mechanisms and proposes fundamental new connections between transition-path theory, linear-response theory, nonequilibrium thermodynamics, and information theory. The author investigates slow, energetically efficient driving protocols that drive a system between conformations corresponding to endpoints of a reaction, aiming to find connections between principles of efficient driving and the spontaneous transition mechanism in the absence of driving. First, an alternative perspective of transition-path theory is developed that unifies it with stochastic thermodynamics to describe flows of entropy, energy, and information during the reaction. This also provides an optimization criterion for selecting collective variables. Next, protocols are designed which invert the magnetization of a 3×3 Ising model with minimal energetic cost,and it is determined that using multiple control parameters allows the system to be driven along a fast-relaxing pathway between reaction endpoints. Finally, the author compares these protocols with the | | 出版日期 | Book 2024 | | 关键词 | Reaction mechanisms; stochastic dynamics; transition-path theory; minimum-work protocols; information th | | 版次 | 1 | | doi | https://doi.org/10.1007/978-3-031-40534-1 | | isbn_softcover | 978-3-031-40536-5 | | isbn_ebook | 978-3-031-40534-1Series ISSN 2190-5053 Series E-ISSN 2190-5061 | | issn_series | 2190-5053 | | copyright | The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Switzerl |
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发表于 2025-3-21 17:05:59
