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Titlebook: Diffusion at Interfaces: Microscopic Concepts; Proceedings of a Wor Michael Grunze,Jeffrey J. Weimer,Hans Jürgen Kreuz Conference proceedin

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楼主: exposulate
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Surface Self-Diffusion, Capillarity, and Surface Stepss of diffusion are discussed involving surface point defects. The connection between macroscopic capillarity treatments of surface shape development by diffusion and the dynamics of evolution of surface atomic step arrays is discussed.
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The Influence of Segregation on the Formation of Cu/Ni Alloy Films by Means of Evaporationimetallic catalysts as Cu/Ni alloys justifies this huge number of experimental /1–49/ and theoretical /50–77/ investigations. Reactivity and selectivity of alloy catalysts in heterogeneously catalyzed reactions are much higher than those of the pure metals. The composition of the surface is the deci
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Surface Properites of a Lead-Tin Alloyaracterized for temperatures up to the bulk liquidus line. These results are discussed in the context of a theory of the variation of alloy surface composition during melting. We also studied the effects of ion bombardment and previous thermal history on the approach to equilibrium.
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Computer Simulation of Segregation and Diffusion at Oxide Interfacesis paper and two examples of recent applications to interface properties are given. Firstly, we consider impurity segregation to the crystal surface. Calculations of isovalent impurities (particularly calcium) in magnesium oxide and aliovalent magnesium in α-alumina are discussed and compared with r
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Towards Hope, Solidarity and Re-humanisation results for these species on Pt(111) and on other metals. For deuterium in the coverage range 0.02 < θ < 0.33, the pre-exponential factor D. = 8 × 10. cm./s, with a diffusion activation energy 3.7 < E. < 4.3 kcal/mol. For CO, E. = 7 kcal/mol, but D. rises from 10. to 10. cm./s between θ = 0.01 and
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Introduction to the Case Studiesons can be made at equilibrium or as the system evolves in time to attain it. The barriers to diffusion can be measured in the two cases and the atomic interactions determined. For the nonequilibrium experiment it is necessary to define a non-equilibrium diffusion coefficient that depends on the mea
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