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Titlebook: Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes; Simple Synthetic Met Yasuomi Yamazaki Book 2022 Springer

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发表于 2025-3-21 17:19:09 | 显示全部楼层 |阅读模式
书目名称Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes
副标题Simple Synthetic Met
编辑Yasuomi Yamazaki
视频video
概述Nominated by Tokyo Institute of Technology as an outstanding Ph.D. book.Presents a number of synthetic methods using diverse coupling reactions to construct photofunctional multinuclear complexes.Incl
丛书名称Springer Theses
图书封面Titlebook: Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes; Simple Synthetic Met Yasuomi Yamazaki Book 2022 Springer
描述.This book presents several helpful synthetic methods for diverse multinuclear complexes. The results described can be used to selectively connect mononuclear as well as multinuclear complexes with other metal complexes to construct valuable photofunctional compounds. Using the new synthetic methods, it was possible to selectively connect several types of metal complexes in a single step under relatively mild reaction conditions. This so-called building block approach utilizes various C–C coupling reactions between metal complexes with functional groups as active moieties. Owing to the large pi-conjugation systems, the multinuclear complexes synthesized using coupling reactions showed a strong absorption ability over a wide range of visible light and long emission lifetimes, which are ideal properties for photosensitizers and light absorbers. By combining these coupling methods with the newly developed hydrogenation reactions, the binding mode of the linkers in multinuclear complexes can be modified in order to tune the photophysical properties and photocatalytic ability. As such, the synthesized multinuclear complexes can be used for various purposes, e.g., as photocatalysts and p
出版日期Book 2022
关键词Photofunctional Multinuclear Metal Complexes; C-C Coupling Reactions; Photochemical Hydrogenation; Phot
版次1
doihttps://doi.org/10.1007/978-981-16-7148-7
isbn_softcover978-981-16-7150-0
isbn_ebook978-981-16-7148-7Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightSpringer Nature Singapore Pte Ltd. 2022
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Selective Synthesis of Various Photofunctional Multinuclear Complexes Using a Combination of the Mit proceed using Pd(OAc). and a tertiary phosphine ligand under an Ar atmosphere. However, it proceeded selectively after the injection of air into the reaction vessel. In this chapter, I report the effect of the air injection on the Pd compounds for the coupling reactions in detail. Interestingly, t
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Synthesis of Novel Multinuclear Complexes for Light-Harvesting Systems Using the Coupling Reactions established. The coupling reactions are potentially applied for connecting with not only mononuclear complexes but also multinuclear complexes. In this chapter, I chose ring-shaped Re(I) multinuclear complexes, which show suitable photophysical and electrochemical properties as photosensitizers, as
发表于 2025-3-22 15:43:58 | 显示全部楼层
Book 2022newly developed hydrogenation reactions, the binding mode of the linkers in multinuclear complexes can be modified in order to tune the photophysical properties and photocatalytic ability. As such, the synthesized multinuclear complexes can be used for various purposes, e.g., as photocatalysts and p
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Development of Synthetic Methods for Novel Photofunctional Multinuclear ComplexesSimple Synthetic Met
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2190-5053 omplexes can be modified in order to tune the photophysical properties and photocatalytic ability. As such, the synthesized multinuclear complexes can be used for various purposes, e.g., as photocatalysts and p978-981-16-7150-0978-981-16-7148-7Series ISSN 2190-5053 Series E-ISSN 2190-5061
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Photochemical and Electrochemical Hydrogenation of ,-Conjugated Bridging Ligands on PhotofunctionalH (3:1:0.1 v/v/v) mixed solution containing the starting metal complexes and a sacrificial electron donor in high yields. The new Ru(II).-Re(I) and Os(II)-Re(I)-Ru(II) trinuclear complexes, which showed high photocatalytic abilities for CO. reduction, were synthesized for the first time by combining
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