书目名称 | Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes |
副标题 | Simple Synthetic Met |
编辑 | Yasuomi Yamazaki |
视频video | |
概述 | Nominated by Tokyo Institute of Technology as an outstanding Ph.D. book.Presents a number of synthetic methods using diverse coupling reactions to construct photofunctional multinuclear complexes.Incl |
丛书名称 | Springer Theses |
图书封面 |  |
描述 | .This book presents several helpful synthetic methods for diverse multinuclear complexes. The results described can be used to selectively connect mononuclear as well as multinuclear complexes with other metal complexes to construct valuable photofunctional compounds. Using the new synthetic methods, it was possible to selectively connect several types of metal complexes in a single step under relatively mild reaction conditions. This so-called building block approach utilizes various C–C coupling reactions between metal complexes with functional groups as active moieties. Owing to the large pi-conjugation systems, the multinuclear complexes synthesized using coupling reactions showed a strong absorption ability over a wide range of visible light and long emission lifetimes, which are ideal properties for photosensitizers and light absorbers. By combining these coupling methods with the newly developed hydrogenation reactions, the binding mode of the linkers in multinuclear complexes can be modified in order to tune the photophysical properties and photocatalytic ability. As such, the synthesized multinuclear complexes can be used for various purposes, e.g., as photocatalysts and p |
出版日期 | Book 2022 |
关键词 | Photofunctional Multinuclear Metal Complexes; C-C Coupling Reactions; Photochemical Hydrogenation; Phot |
版次 | 1 |
doi | https://doi.org/10.1007/978-981-16-7148-7 |
isbn_softcover | 978-981-16-7150-0 |
isbn_ebook | 978-981-16-7148-7Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
issn_series | 2190-5053 |
copyright | Springer Nature Singapore Pte Ltd. 2022 |