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Titlebook: Desorption Induced by Electronic Transitions DIET IV; Proceedings of the F Gerhard Betz,Peter Varga Conference proceedings 1990 Springer-Ve

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Photochemistry of Halogenated Molecules Adsorbed on Ag(111)The UV photodissociation of several halogen-containing molecules, adsorbed on Ag{111}, is described. Attention is focused on Cl.CO.
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Dissociative Desorption of CH3I by UV-Laser Radiation: Kinetic and Internal Energy of the Neutral FrShort wavelength laser radiation is used to initiate photodissociation of condensed molecules and to detect the emitted particles species-, energy- and state-selectively. A case study with condensed methyliodine shows that direct dissociative photodesorption can be identified. A comparison with the gas phase process reveals several differences.
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Substrate Mediated Photodissociation of NO2/N2O4 Adsorbed on Pd(111)f the NO molecules released into the gas phase and determination of the yield as function of angle and polarization provide clear evidence that the dominant primary process consists in electronic excitation of the metallic substrate rather than in direct absorption by the adsorbate.
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https://doi.org/10.1007/978-3-642-84145-3Helium-Atom-Streuung; Photophysics; Surface Physics and Chemistry; Surface science; chemistry; surface; su
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978-3-642-84147-7Springer-Verlag Berlin Heidelberg 1990
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0931-5195 Overview: 978-3-642-84147-7978-3-642-84145-3Series ISSN 0931-5195 Series E-ISSN 2198-4743
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Excitation Lifetimes and Excited-State Forces in Chemisorbed Moleculese. For NO. , consideration of the photoelectron spectrum, electronic structure, and excitation lifetimes allows us to assign the two dominant dissociation channels to specific one and two hole excitations. While the holes occupy non-bonding molecular orbitals (MOs), we find charge-transfer screening
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