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Titlebook: Design, Synthesis and Characterization of new Supramolecular Architectures; Massimo Baroncini Book 2011 The Editor(s) (if applicable) and

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发表于 2025-3-21 17:22:43 | 显示全部楼层 |阅读模式
书目名称Design, Synthesis and Characterization of new Supramolecular Architectures
编辑Massimo Baroncini
视频videohttp://file.papertrans.cn/269/268831/268831.mp4
概述Nominated by the University of Bologna for a Springer Theses Prize..This research addresses a large number of open problems in the nanosciences..Some of the most advanced and studied supramolecular sy
丛书名称Springer Theses
图书封面Titlebook: Design, Synthesis and Characterization of new Supramolecular Architectures;  Massimo Baroncini Book 2011 The Editor(s) (if applicable) and
描述This thesis focuses on the bottom-up design, construction and operation of supramolecular systems capable of behaving as devices and machines on the molecular scale, which is a topic of great interest in nanoscience and a fascinating challenge in nanotechnology. In particular, the systems investigated here include: polyviologen dendrimers capable of behaving as hosts and chargestoring devices; molecular machines based on pseudorotaxanes/rotaxanes and operated by photoinduced proton transfer, or photoisomerization reactions; and a simple unimolecular multiplexer/demultiplexer. The systems have been characterized using a variety of techniques including absorption and emission spectra, laser flash photolysis, NMR spectroscopy, electrochemical experiments, stopped flow measurements. This research addresses a large number of open problems in the nanosciences, dealing with a wide range of the most advanced applications of supramolecular systems.
出版日期Book 2011
关键词Molecular Logic; Nanotechnology; Rotaxanes Chemistry; Supramolecular Chemistry; Viologen Dendrimers
版次1
doihttps://doi.org/10.1007/978-3-642-19285-2
isbn_softcover978-3-642-26791-8
isbn_ebook978-3-642-19285-2Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightThe Editor(s) (if applicable) and The Author(s), under exclusive license to Springer-Verlag GmbH, DE
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Supramolecular Architectures,ng pattern and with repeating units constituting the branching points. The term . refers to its characteristic tree-like structure and it derives from the Greek word . (tree) and . (part). From a topological viewpoint, dendrimers contain three different regions: core, branches and surface. Each repe
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Materials and Methods,iterature procedures. Thin-layer chromatography (TLC) was performed on aluminum sheets coated with silica gel 60F (Merck 5554). The plates were inspected by UV light. Column chromatography was performed on silica gel 60 (Merck 40–60 nm, 230–400 mesh). High-performance liquid chromatography (HPLC) gr
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Dendrimers: Polyviologen Dendrimers as Hosts and Charge-Storing Devices, contain selected chemical units in predetermined sites of their structure (core, branches, periphery) whose mutual interactions can lead to unusual, sometimes unpredictable, chemico-physical properties resulting in a wide range of potential applications. Dendrimers containing photoactive and/or ele
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Dendrimers: Tweezering the Core of Dendrimers: Medium Effect on the Kinetic and Thermodynamic Propeecular recognition phenomena imply the formation of supramolecular species characterized by peculiar structural, thermodynamic, and kinetic features determined by molecular information stored in receptor and substrate(s) that lead to selective binding. Stability of the supramolecular host–guest comp
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Self-Assembly of Calix[6]arene-Diazapyrenium Pseudorotaxanes: Interplay of Molecular Recognition ant systems represent convenient precursors for the synthesis of more complex interlocked structures, such as rotaxanes and catenanes, which can operate as simple molecular machines. Essentially, the functioning mode of a pseudorotaxane consists of an external stimulus-promoted reversible threading–de
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2190-5053 , laser flash photolysis, NMR spectroscopy, electrochemical experiments, stopped flow measurements. This research addresses a large number of open problems in the nanosciences, dealing with a wide range of the most advanced applications of supramolecular systems.978-3-642-26791-8978-3-642-19285-2Series ISSN 2190-5053 Series E-ISSN 2190-5061
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