| 书目名称 | Design of Crystal Structures Using Hydrogen Bonds on Molecular-Layered Cocrystals and Proton–Electro | | 编辑 | Masaki Donoshita | | 视频video | | | 概述 | Nominated as an outstanding Ph.D. thesis by Kyoto University, Japan.Describes the control over the relative arrangement of hydrogen-bonded assemblies.Presents various methods of characterization and e | | 丛书名称 | Springer Theses | | 图书封面 |  | | 描述 | This thesis addresses the design of crystal structures using hydrogen bonds. In particular, it focuses on the design of functionalities and the control over the packing of molecular assemblies, based on molecular designs..Firstly, the synthesis and evaluation of a proton–electron mixed conducting charge transfer salt is reported. Focusing on the difference in the strength of hydrogen bonds and weaker intermolecular interactions, a system was rationally designed and constructed where electron-conducting molecular wires were encapsulated within a proton-conducting matrix. Next, the investigation of structural phase transitions in a cocrystal consisting of hydrogen-bonded two-dimensional molecular assemblies is reported. Drastic rearrangements of hydrogen-bonded molecular assemblies in the cocrystal led to single-crystal-to-single-crystal phase transitions, resulting in anisotropic changes in the crystal shape. Furthermore, chemical modification of a component molecule in the cocrystal is reported. The modification afforded control over the stacking patterns of the two-dimensional molecular assemblies, i.e., sheets, and the mechanism was discussed considering the intersheet intermolec | | 出版日期 | Book 2024 | | 关键词 | Hydrogen Bond; Crystal Structure; Cocrystal; Phase Transition; Molecular Conductor | | 版次 | 1 | | doi | https://doi.org/10.1007/978-981-99-7062-9 | | isbn_softcover | 978-981-99-7064-3 | | isbn_ebook | 978-981-99-7062-9Series ISSN 2190-5053 Series E-ISSN 2190-5061 | | issn_series | 2190-5053 | | copyright | The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor |
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发表于 2025-3-21 17:48:23
