| 书目名称 | Design and Precise Synthesis of Thermoresponsive Polyacrylamides |
| 编辑 | Keita Fuchise |
| 视频video | |
| 概述 | Nominated by Hokkaido University as an outstanding Ph.D. thesis.Explains easy and versatile methods to control the thermoresponsive properties of polyacrylamides.Furnishes useful results for further d |
| 丛书名称 | Springer Theses |
| 图书封面 |  |
| 描述 | .In this thesis, the author describes versatile and easy-to-use methods to control the properties of thermoresponsive polyacrylamides by developing novel synthetic methods for end-functionalized poly(.N.-isopropylacrylamide) (PNIPAM) and block copolymers of poly(.N,N.-diethylacrylamide) (PDEAA). The synthesis of various urea end-functionalized PNIPAMs was achieved by the atom transfer radical polymerization (ATRP) and the click reaction. The phase transition temperature of PNIPAM in water was controlled depending on the strength of the hydrogen bonding of the urea groups introduced at the chain end of the polymer. Novel living polymerization methods for .N.,.N.-dimethylacrylamide and .N.,.N.-diethylacrylamide were developed by group transfer polymerization (GTP) using a strong Brønsted acid as a precatalyst and an amino silyl enolate as an initiator. This process enabled the precise synthesis of PDEAA and its block copolymers—namely, thermoresponsive amphiphilic block copolymers and double-hydrophilic block copolymers.. |
| 出版日期 | Book 2014 |
| 关键词 | Click Reaction; Group Transfer Polymerization (GTP); Organocatalysts; Poly(N,N-diethylacrylamide) (PDEA |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-4-431-55046-4 |
| isbn_softcover | 978-4-431-56403-4 |
| isbn_ebook | 978-4-431-55046-4Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
| issn_series | 2190-5053 |
| copyright | Springer Japan 2014 |
发表于 2025-3-21 16:32:04
