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Titlebook: Current Challenges on Large Supramolecular Assemblies; George Tsoucaris Book 1999 Springer Science+Business Media Dordrecht 1999 adsorptio

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书目名称Current Challenges on Large Supramolecular Assemblies
编辑George Tsoucaris
视频video
丛书名称Nato Science Series C:
图书封面Titlebook: Current Challenges on Large Supramolecular Assemblies;  George Tsoucaris Book 1999 Springer Science+Business Media Dordrecht 1999 adsorptio
描述The objectives of the ARW were: - identifying areas and highlighting approaches by which large Supramolecular (SM) Assemblies can be synthesised - reviewing and combining methods to characterise and analyse such assemblies. The first part of the ARW is devoted to reviewing synthetic achievements in recent years for several families of SM compounds, and to bringing out principles for crystal structure design, including novel quantum mechanical methods. Synthesis pertains both to the chemical synthesis of components for SM assembly, and to the subsequent assembly process based on complementarity and non-covalent interactions. The elaboration of multiple recognition "algorithms" concurrently employed (for instance, 1t-1t and hydrogen bonds) has recently reached a high degree of sophistication in the sequence: Molecules -7 Supermolecule -7 SM array -7 Crystal or Conglomerate Novel Large Assemblies comprise synthetic entities with molecular weight as high as 15000, and hybrid SM assemblies between synthetic molecules and DNA. Further developments are foreseen at a higher level of organisation, such as between supermolecules or with electromagnetic fields in photochemical processes. Crea
出版日期Book 1999
关键词adsorption; bonding; chemical structure; chemistry; colloid; crystal; crystallography; fullerenes; hydrogen;
版次1
doihttps://doi.org/10.1007/978-94-011-5284-6
isbn_softcover978-94-010-6224-4
isbn_ebook978-94-011-5284-6Series ISSN 1389-2185
issn_series 1389-2185
copyrightSpringer Science+Business Media Dordrecht 1999
The information of publication is updating

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,The Role of Charge Assisted C-Hδ+ ---Oδ- and C-Hδ+---Fδ− Hydrogen Bonds in Organometallic Crystals,-H---F type have also been investigated in organometallic salts containing PF.. and BF.. anions. These weak interactions are reinforced by the opposite charge present on the ionic components, and have been shown to be responsible for the crystal stability and the phase transitional behaviour of some organometallic systems.
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Plato and the Platonism of Anne Conwayeloping science or a non-science. The nature of a paradigm is to possess intellectual and physical components and connections that are accepted as necessary and sufficient to describe all observable phenomena.
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Katherine Lorenz,Rebecca M. Hayess of studying the processes that lead to self-assembly and that connect the product to possible pre-cursor states. Developments in the NMR spectroscopy of noble gases has made it particularly attractive to focus on the longstanding and ever important problem of gas hydrate formation..
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Non-Covalent Synthesis and Characterization of Large Supramolecular Assemblies,lies with molecular weights up to 10,000 Dalton have been realized. The combination of hydrogen bonding and metal-coordination has been achieved in the synthesis of metallodendrimers with a hydrogen-bonded core.
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Supramolecular Architectures on Liquid Surfaces. from 2-D Assemblies to 3-D Crystals, that has emerged over the last decade. The thin-film clusters generated at the air-solution interface can be deposited on solid surfaces and then analyzed by other methods such as scanning force microscopy (SFM) and cryoelectron microscopy (cryo-TEM).
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