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Titlebook: Crystal Chemistry of High-Tc Superconducting Copper Oxides; Bernard Raveau,Claude Michel,Daniel Groult Textbook 1991 Springer-Verlag Berli

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书目名称Crystal Chemistry of High-Tc Superconducting Copper Oxides
编辑Bernard Raveau,Claude Michel,Daniel Groult
视频video
丛书名称Springer Series in Materials Science
图书封面Titlebook: Crystal Chemistry of High-Tc Superconducting Copper Oxides;  Bernard Raveau,Claude Michel,Daniel Groult Textbook 1991 Springer-Verlag Berli
描述The recent discovery of high-temperature superconductivity in copper­ based oxides is an event of major importance not only with respect to the physical phenomenon itself but also because it definitely shows that solid state chemistry, and especially the crystal chemistry of oxides, has a crucial place in the synthesis and understanding of new materials for future appli­ cations. The numerous papers published in the field of high Tc supercon­ ductors in the last five years demonstrate that the great complexity of these materials necessitates a close collaboration between physicists and solid state chemists. This book is based to a large extent on our experience of the crystal chemistry of copper oxides, which we have been studying in the laboratory for more than twelve years, but it also summarizes the main results which have been obtained for these compounds in the last five years relating to their spectacular superconducting properties. We have focused on the struc­ ture, chemical bonding and nonstoichiometry of these materials, bearing in mind that redox reactions are the key to the optimization of their supercon­ ducting properties, owing to the importance of the mixed valence
出版日期Textbook 1991
关键词Copper Oxides; Defects; Festkörperchemie; Layered Cuprate; Radiation Damage; Superconductivity; chemistry;
版次1
doihttps://doi.org/10.1007/978-3-642-83892-7
isbn_softcover978-3-642-83894-1
isbn_ebook978-3-642-83892-7Series ISSN 0933-033X Series E-ISSN 2196-2812
issn_series 0933-033X
copyrightSpringer-Verlag Berlin Heidelberg 1991
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Phases of the Systems A-La-Ca-Cu-O and A-Y-Ca-Cu-O (A = Ca, Sr, Ba): Structural Aspects, that contribute to the framework of MO. polyhedra should exhibit a mixed valence in order to obtain metallic or semimetallic conductivity. This concept is of central importance in the search for new materials with such physical properties. It leads to the conclusion that the metal atom M should pre
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Electron Transport Properties Connected with Oxygen Nonstoichiometry, structure and the perovskite structure, present various electron transport properties leading to semiconducting, metallic or superconducting behavior. These properties are due to copper, which exhibits a mixed valence in these oxides that seems to be enhanced by the localization of copper in the pe
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Substitutions in La2CuO4-Type and YBa2Cu3O7-Type Superconductors,perties of the La. CuO. - and YBa. Cu. O. -type structural families. It is, of course, not possible to discuss here all these results, in spite of their great importance from the physical viewpoint. It should, however, be emphasized that it is very difficult to interpret many of these papers, in spi
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Bismuth, Thallium and Lead Superconducting Cuprates,, even when the lanthanide is a magnetic cation, has encouraged the investigation of the related quaternary oxides involving copper, an alkaline earth element and a trivalent element other than a rare earth. Two families were discovered successively: the bismuth copper oxides and the thallium copper
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Wireless Optical Intensity Channels study of chalcogenides and, more recently, to organic compounds. Up until 1986, superconductivity was limited to low temperatures and, in particular, it was linked to the use of liquid helium: the highest critical temperature that had been observed was 23.3 K for Nb.Ge. In spite of this handicap, s
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