Titlebook: Coordination Chemistry; Basics and Current T Birgit Weber Textbook 20231st edition The Editor(s) (if applicable) and The Author(s), under e

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lready been mentioned in the introduction of the 18-electrons rule (Sect. .). The formulation of such bonds deviates greatly from Werner’s ideas about the molecular chemistry of transition metals and the breakthrough did not occur until the 1950s, when X-ray structural analysis clearly demonstrated

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Women in Society and in the Novel,s the possibility to realize different oxidation states. Many of these compounds have unpaired electrons in the d or f orbitals. These are involved in bonding, especially in the case of the d orbitals, and are influenced by ligands. This means that the coordination environment around the metal cente

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Von der Schule in die Arbeitsweltthese metal ions are bound to the protein environment in the form of complexes. In this chapter, the aspects of interest with regard to coordination chemistry are discussed on the basis of two examples.

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Von der Schule in die Arbeitswelt organometallic chemistry. This is underlined by the large number of Nobel Prizes awarded for catalytic processes. In the following, the first section will discuss the example of polymerization catalysis and its discovery. The second section of this chapter deals with photocatalysis, which is highly

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Chemical reactions can be divided into two categories, substitution reactions and redox reactions. In the previous chapter, we considered the stability of complexes and dealt with ligand exchange, i.e. substitution reactions. In the following, we will deal with the second major class of reactions of complexes, the redox reactions.

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