| 书目名称 | Cooperative Phenomena in Jahn—Teller Crystals |
| 编辑 | Michael D. Kaplan,Benjamin G. Vekhter |
| 视频video | |
| 丛书名称 | Modern Inorganic Chemistry |
| 图书封面 |  |
| 描述 | This book by Kaplan and Vekhter brings together the molecular world of the chemist with the condensed matter world of the physicist. Prior to the collapse of the Soviet Union, chemists in the West devoted lit to relationships between molecular electronic structure and tle attention solid-state vibronic phenomena. Treating quantum mechanical problems wherein the adiabatic Born-Oppenheimer approximation fails was done by "brute force. " With bigger and better computers available in the West, molecular orbital calculations were done on observed and conceived static structures with little concern for any cooperativity of vibrational behavior that might connect these states. While it had long been understood in the West that situations do occur in which different static structures are found for molecules that have identical or nearly identical electronic structures, little attention had been paid to understanding the vibrational states that could connect such structures. It was easier to calculate the electronic structure observed with several possible distortions than to focus on ways to couple electronic and vibrational behavior. In the former Soviet Union, computational power was no |
| 出版日期 | Book 1995 |
| 关键词 | chemistry; crystal; phase diagram |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-1-4615-1859-4 |
| isbn_softcover | 978-1-4613-5755-1 |
| isbn_ebook | 978-1-4615-1859-4Series ISSN 0891-4540 Series E-ISSN 2945-5057 |
| issn_series | 0891-4540 |
| copyright | Springer Science+Business Media New York 1995 |
发表于 2025-3-21 17:46:52
