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Titlebook: Contemporary Quantum Chemistry; An Introduction J. Goodisman Book 1977 Plenum Press, New York 1977 Atom.chemistry.inorganic chemistry.mecha

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发表于 2025-3-21 19:16:51 | 显示全部楼层 |阅读模式
书目名称Contemporary Quantum Chemistry
副标题An Introduction
编辑J. Goodisman
视频video
图书封面Titlebook: Contemporary Quantum Chemistry; An Introduction J. Goodisman Book 1977 Plenum Press, New York 1977 Atom.chemistry.inorganic chemistry.mecha
描述Some knowledge of the principles of quantum mechanics and how they are applied to theoretical chemistry, it is generally agreed, should be part of the education of all chemists. This instruction in quantum chemistry is either added to the more traditional topics of physical chemistry or given separately; at Syracuse University it forms the third semester of the physical chemistry sequence. While a wide variety of textbooks and monographs on the subject of quantum chemistry exists, the author of the present text found that none of them was satisfactory for his purposes, i. e. , none fit his ideas of what subjects should be discussed and in what way. This book is presented with the hope that others with similar experiences will agree with him and endorse his conclusions. The undergraduate student to whom our attentions are directed is a chemistry major, but probably will not go on to graduate school in physical chemistry. He may take several more chemistry courses as an undergraduate and then seek a position in industry, or perhaps he will do graduate work in organic or inorganic chemistry. (Of course, one never stops hoping that, as a result of this first course, he will decide to l
出版日期Book 1977
关键词Atom; chemistry; inorganic chemistry; mechanics; organic chemistry; physical chemistry; quantum chemistry;
版次1
doihttps://doi.org/10.1007/978-1-4684-2268-9
isbn_softcover978-1-4684-2270-2
isbn_ebook978-1-4684-2268-9
copyrightPlenum Press, New York 1977
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The Wave Equation,ement of the string off the . axis, as a function of distance along the . axis (see Figure 2.1). If this were a water wave, we would interpret . as the height of the water rather than as the displacement of the string.
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The Variational Method and the Harmonic Oscillator,here are very few Schrodinger equations for which one can find solutions in the form of simple analytical functions. It is necessary to resort to approximate techniques. The most important of these is the variational method, which we will discuss in this chapter. Its use will be illustrated by apply
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Three-Dimensional Problems,rse have to confront several particles in three dimensions. In this chapter, we remove one restriction by considering three-dimensional one-particle problems. This will enable us to treat one-electron atomic systems in Chapter 6. Then in Chapter 7, we will turn to the quantum-mechanical treatment of
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Identical Particles,will be more complicated, and in this chapter we will find out how. In Chapter 8, we will study many-electron atoms using our knowledge of the one-electron atom. This is typical: we usually try to break down a many-electron problem into one-electron problems, thus taking the electrons one at a time.
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Atomic Structure,n Chapter 7, will play an important role. In case you haven’t noticed, it really didn’t do anything (except complicate our calculation) for the helium atom. Its consequences will be important for the three-electron atom and beyond.
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The Hydrogen Molecule,om these we will generalize to obtain rules to be used in the more complicated cases, for which we will not explicitly carry out calculations. The simplest cases are H.+(two protons and one electron) and H. (two protons and two electrons). Our main goal is to find out what makes these molecules stab
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