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Titlebook: Consequences of Combinatorial Studies of Positive Electrodes for Li-ion Batteries; Eric McCalla Book 2014 Springer International Publishin

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书目名称Consequences of Combinatorial Studies of Positive Electrodes for Li-ion Batteries
编辑Eric McCalla
视频video
概述Nominated by Dalhousie University as an outstanding PhD thesis.In-depth discussion of quantitative analysis of XRD data from combinatorial samples.Contains phase diagrams of high precision.Covers high
丛书名称Springer Theses
图书封面Titlebook: Consequences of Combinatorial Studies of Positive Electrodes for Li-ion Batteries;  Eric McCalla Book 2014 Springer International Publishin
描述Li-Co-Mn-Ni oxides have been of extreme interest as potential positive electrode materials for next generation Li-ion batteries.  Though many promising materials have been discovered and studied extensively, much debate remains in the literature about the structures of these materials. There is no consensus as to whether the lithium-rich layered materials are single-phase or form a layered-layered composite on the few nanometer length-scales. Much of this debate came about because no phase diagrams existed to describe these systems under the synthesis conditions used to make electrode materials.  Detailed in this thesis are the complete Li-Co-Mn-O and Li-Mn-Ni-O phase diagrams generated by way of the combinatorial synthesis of mg-scale samples at over five hundred compositions characterized with X-ray diffraction. Selected bulk samples were used to confirm that the findings are relevant to synthesis conditions used commercially. The results help resolve a number of points of confusion and contradiction in the literature. Amongst other important findings, the compositions and synthesis conditions giving rise to layered-layered nano-composites are presented and electrochemical result
出版日期Book 2014
关键词Combinatorial Science; Li-Co-Mn-O systems; Li-Mn-Ni-O systems; Li-ion Batteries; Positive Electrodes; XRD
版次1
doihttps://doi.org/10.1007/978-3-319-05849-8
isbn_softcover978-3-319-38317-0
isbn_ebook978-3-319-05849-8Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightSpringer International Publishing Switzerland 2014
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Optimization of the Synthesis of Combinatorial Samples,the main source of lithium loss was the decomposition of lithium carbonate that failed to react with the nickel oxide structure. The fact that the formation of LiNiO. was hindered significantly in air was attributed to the presence of constituents in air other than oxygen and nitrogen, the likeliest
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,Combinatorial Studies of the Spinel and Rocksalt Regions in the Li–Mn–Ni–O System, and when quenched or regular cooled in oxygen. All samples discussed here either contained one or two phases; and no evidence for nonequilibrium behaviour was seen. Two-phase fits in the coexistence regions were used to determine lattice parameters to allow the drawing of tie-lines. The lever rule
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Materials Near the Layered Boundary,under various oxygen partial pressures and were related to features in the phase diagram determined previously. Materials made with 5 . excess lithium (at point B. in Fig. .) were found to stay single phase even when the regular cooling rate of 5–10 °C/min was used. These single-phase layered materi
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Conclusions and Future Works,nched from 800 °C. Some approximations were made to join the two faces since the Li-Co-Mn-O face was synthesized in air while the nickel containing samples were made in oxygen. Nonetheless, the two faces join quite well. The pyramid strongly suggests that both single-phase regions of importance for
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