书目名称 | Consequences of Combinatorial Studies of Positive Electrodes for Li-ion Batteries |
编辑 | Eric McCalla |
视频video | |
概述 | Nominated by Dalhousie University as an outstanding PhD thesis.In-depth discussion of quantitative analysis of XRD data from combinatorial samples.Contains phase diagrams of high precision.Covers high |
丛书名称 | Springer Theses |
图书封面 |  |
描述 | Li-Co-Mn-Ni oxides have been of extreme interest as potential positive electrode materials for next generation Li-ion batteries. Though many promising materials have been discovered and studied extensively, much debate remains in the literature about the structures of these materials. There is no consensus as to whether the lithium-rich layered materials are single-phase or form a layered-layered composite on the few nanometer length-scales. Much of this debate came about because no phase diagrams existed to describe these systems under the synthesis conditions used to make electrode materials. Detailed in this thesis are the complete Li-Co-Mn-O and Li-Mn-Ni-O phase diagrams generated by way of the combinatorial synthesis of mg-scale samples at over five hundred compositions characterized with X-ray diffraction. Selected bulk samples were used to confirm that the findings are relevant to synthesis conditions used commercially. The results help resolve a number of points of confusion and contradiction in the literature. Amongst other important findings, the compositions and synthesis conditions giving rise to layered-layered nano-composites are presented and electrochemical result |
出版日期 | Book 2014 |
关键词 | Combinatorial Science; Li-Co-Mn-O systems; Li-Mn-Ni-O systems; Li-ion Batteries; Positive Electrodes; XRD |
版次 | 1 |
doi | https://doi.org/10.1007/978-3-319-05849-8 |
isbn_softcover | 978-3-319-38317-0 |
isbn_ebook | 978-3-319-05849-8Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
issn_series | 2190-5053 |
copyright | Springer International Publishing Switzerland 2014 |