Titlebook: Complexity in Chemistry and Beyond: Interplay Theory and Experiment; New and Old Aspects Craig Hill,Djamaladdin G. Musaev Conference proce

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https://doi.org/10.1007/978-3-658-11460-2hat antioxidants can be formulated that have synergistic activity. One example of this phenomenon is the combination in one molecule of phenolsulphide and aminosulphide moieties, which results in an antioxidant with superior activity for the critical hydroperoxide decomposition process compared to molecules containing either moiety alone.

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Statische Berechnung von KesselbödenO. is significant and attributable to anion–anion repulsion within the successor-complex ion pairs formed between the negatively charged POM anions and O.. These findings were followed by the discovery of a concerted proton–electron (CPET) pathway for electron transfer to O. at lower pH values (<1).

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https://doi.org/10.1007/978-3-663-05498-6sts must be connected with other functional units (light absorbers, reduction catalysts and key interfaces) to realize nanostructures or devices that efficiently produce solar fuels. Unfortunately these functional units are dependent on each other and also on several factors, thus predicting overall operation is a challenge in complexity.

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Electron Transfer to Dioxygen by Keggin Heteropolytungstate Cluster Anions,O. is significant and attributable to anion–anion repulsion within the successor-complex ion pairs formed between the negatively charged POM anions and O.. These findings were followed by the discovery of a concerted proton–electron (CPET) pathway for electron transfer to O. at lower pH values (<1).

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Encapsulated Water Molecules in Polyoxometalates: Insights from Molecular Dynamics,e case of Mo.-SO. and Mo.-HCO., our simulations showed that encapsulated water molecules self-assemble dynamically in shell structures, which are strongly affected by slightly increasing the volume of the capsule. Water in the cavities is structurally closer to ice water than to liquid water, as it is unable to diffuse as liquid water does.

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Antioxidants of Hydrocarbons: From Simplicity to Complexity,hat antioxidants can be formulated that have synergistic activity. One example of this phenomenon is the combination in one molecule of phenolsulphide and aminosulphide moieties, which results in an antioxidant with superior activity for the critical hydroperoxide decomposition process compared to molecules containing either moiety alone.