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Titlebook: Chiral Lewis Acids; Koichi Mikami Book 2018 Springer International Publishing AG 2018 Alder Ene Reaction.Bimetallic Lexis Acids.Broensted

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Preference from Priorities: Dynamic Logic discovery of the metal-free activations, whereas the FLP-mediated hydrogen activation is the most prominent. So far, the metal-free hydrogenation is the most studied application of FLP chemistry and highly efficient methodologies for a number of unsaturated substrates have been developed. This chap
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https://doi.org/10.1007/978-3-319-70806-5Alder Ene Reaction; Bimetallic Lexis Acids; Broensted Acid Lewis Base Hybrids; Carbophilic Gold Lewis A
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978-3-030-09994-7Springer International Publishing AG 2018
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A Two-Level Perspective on Preferencely important role in asymmetric reactions. Their broad applicability to cycloaddition and condensation reactions based on close encountered associations of Lewis base reactants with these chiral Lewis acid catalysts provides architecturally confined complexes that provide high stereocontrol in their chemical reactions.
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https://doi.org/10.1007/978-94-007-1344-4different classes of gold complexes have been identified and their application in enantioselective catalysis discussed: (1) chiral bisphosphine digold complexes, (2) monogold complexes of chiral monodentate phosphorous ligands, (3) chiral aminocarbene gold complexes, and (4) gold complexes containing chiral phosphate counterions.
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,Brønsted Acid/Lewis Base Hybrid Complexes,B(C.F.)., for promoting the anomalous .-selective Diels–Alder reaction. The specific mechanism and deep insights into the possible key intermediates are discussed on the basis of rational design of chiral supramolecular Brønsted acid/Lewis base hybrid catalysts as artificial enzymes.
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