| 书目名称 | Chiral Diazaligands for Asymmetric Synthesis |
| 编辑 | Marc Lemaire,Pierre Mangeney |
| 视频video | |
| 概述 | Provides the broad scientific readership with comprehensive summary and critical overview of a topic in organometallic chemistry.Research in this rapidly developing transdisciplinary field is having p |
| 丛书名称 | Topics in Organometallic Chemistry |
| 图书封面 |  |
| 描述 | .The use of phosphine derivatives has historically induced the tremendous development of catalysis (both non-asymmetric and asymmetric). Although the chemistry of amines is more documented, the use of nitrogen-containing ligands only appeared recently. Nevertheless, during the last ten years, the results describing chiral diamine preparations and their uses in asymmetric catalysis and synthesis are increasing faster than their phosphorus counterparts. The reader will find in this volume the most recent methods for the synthesis of chiral diamines as well as their applications in asymmetric catalysis of CC bond formation. Particular attention will be given to spartein and derivatives of such diamines. Recently, the particular properties and the chemistry of amines allowed to obtain catalysts easy to separate and recycle and new types of ligands such as diaminocarbenes, ureas and thioureas. Finally, the complexing properties of some diamines allowed the formation of complexes with chirality "at the metal " which is of major theoretical interest and presents numerous potential applications.. |
| 出版日期 | Book 2005 |
| 关键词 | Organometallic chemistry; catalysis; medicinal chemistry; metals |
| 版次 | 1 |
| doi | https://doi.org/10.1007/b105252 |
| isbn_softcover | 978-3-642-06538-5 |
| isbn_ebook | 978-3-540-31442-4Series ISSN 1436-6002 Series E-ISSN 1616-8534 |
| issn_series | 1436-6002 |
| copyright | Springer-Verlag Berlin Heidelberg 2005 |
发表于 2025-3-21 16:43:31
