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Titlebook: Chemistry of Precious Metals; S. A. Cotton Book 1997 Chapman & Hall 1997 Coordination Chemistry.Gold.Iridium.Osmium.Palladium.Platin.Rhodi

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Book 1997elements within its compass (S.A. Cotton and F.A. Hart, The Heavy Transition Elements, Macmillan, 1975). This volume shares the same aim of covering the descriptive chemistry of silver, gold and the six platinum metals in some detail at a level suitable for advanced undergraduate and postgraduate st
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Rhodium and iridium,for cobalt, their lighter homologue (factors responsible include the increased stability of the +3 state consequent upon the greater stabilization of the low spin d. configuration as 10 Dq increases).
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Book 1997igands are generally excluded. Their inclusion would have increased the length of the book considerably and, moreover, their recent chemistry has been extensively and expertly reviewed in the new Comprehensive Organometallic Chemistry, II, eds G. Wilkinson, F.G.A. Stone and E.W. Abel, Pergamon, Oxford, 1995.
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https://doi.org/10.1007/978-3-319-06647-9ates are the most important, along with +4 for osmium; however, there is a considerable chemistry of the MO. (‘osmyl’ and ‘rutheny’) and M ≡ N. groups, as well as the ‘classical’ hydride complexes OsH.(PR.)., which also involve osmium(VI).
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Silver and gold,tate is the most important, for silver it is the +1 state and, though oxidation states between -1 and +7 are claimed, for gold it is the +1 and +3 states that dominate its chemistry. The types of compound are summarized in Table 4.1.
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